"Machalick\u00FD, Old\u0159ich" . . "9"^^ . "540409" . "The kinetics of heterogeneous catalytic reductive amination of cyclopentanone has been studied on a pilot plant PARR autoclave. N-cyclopentyliminocyclopentane was detected as the main intermediate in a reaction mixture. It was found that, at the given conditions, the main intermediate does not form the undesirable N,N-dicyclopentylamine but undergoes slow hydrolysis, and the desired product, cyclopentylamine, results in a good yield. Slight amounts of by-products such as cyclopentanole and N,N-dicyclopentylamine were obtained. The experimental data were confronted with the suggested kinetic model."@en . . . "Reduktivn\u00ED aminace cyklopentanonu"@cs . "Applied catalysis A-General" . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . . "0926-860X" . "Z(MSM0021627501)" . "286" . . "Hr\u00E1dkov\u00E1, Kv\u011Btoslava" . "Kubec, Petr" . "Hrdina, Radim" . . . "202-210" . . "Dole\u017Eal, Petr" . "The kinetics of heterogeneous catalytic reductive amination of cyclopentanone has been studied on a pilot plant PARR autoclave. N-cyclopentyliminocyclopentane was detected as the main intermediate in a reaction mixture. It was found that, at the given conditions, the main intermediate does not form the undesirable N,N-dicyclopentylamine but undergoes slow hydrolysis, and the desired product, cyclopentylamine, results in a good yield. Slight amounts of by-products such as cyclopentanole and N,N-dicyclopentylamine were obtained. The experimental data were confronted with the suggested kinetic model." . "Reductive amination of Cyclopentanone"@en . . . . . "2"^^ . "[968A9F54B34D]" . "2" . "Reductive amination of Cyclopentanone" . "Cyclopentanone; Cyclopentylamine; N-cyclopentyliminocyclopentane; Heterogeneous catalytic reductive amination; Kinetics"@en . . . "Kinetika heterogenn\u00ED katalytick\u00E9 reduktivn\u00ED aminace cyklopentanonu byla studov\u00E1na na poloprovozn\u00EDm aktokl\u00E1vu PAAR. N-cyklopentyliminocykolopentanon byl detekov\u00E1n jako hlavn\u00ED intermediate v reak\u010Dn\u00ED sm\u011Bsi. Bylo zji\u0161t\u011Bno, \u017Ee za dan\u00FDch podm\u00EDnek nevznik\u00E1 z hlavn\u00EDho intermedi\u00E1tu ne\u017E\u00E1douc\u00ED N,N-dicykopentylamin ale tento podl\u00E9h\u00E1 pomal\u00E9 hydrol\u00FDze a vznik\u00E1 \u017E\u00E1dan\u00FD cyklopentylamin v dobr\u00E9m v\u00FDt\u011B\u017Eku. Bala z\u00EDks\u00E1na mal\u00E1 mno\u017Estv\u00ED vedlej\u0161\u00EDch l\u00E1tek jako cyklopentanol a N,N-dicyklopentylamin. Experiment\u00E1ln\u00ED data byla konfrontov\u00E1na s navr\u017Een\u00FDm kinetick\u00FDm modelem."@cs . . "Pavelek, Martin" . "7"^^ . "Reductive amination of Cyclopentanone"@en . "Reductive amination of Cyclopentanone" . . . "RIV/00216275:25310/05:00002684" . "RIV/00216275:25310/05:00002684!RIV08-MSM-25310___" . . "\u0160ul\u00E1kov\u00E1, Romana" . "Reduktivn\u00ED aminace cyklopentanonu"@cs . "25310" .