"1"^^ . "Polarografie ve studiu chenick\u00E9ho mikro-mechanizmu iniciace polynitroaren\u016F"@cs . . "RIV/00216275:25310/04:00003527" . "RIV/00216275:25310/04:00003527!RIV08-MSM-25310___" . "25310" . . "9"^^ . "2"^^ . "Polarografie ve studiu chenick\u00E9ho mikro-mechanizmu iniciace polynitroaren\u016F"@cs . . "171-179" . "580082" . . "Polarography in the Study of Chemical Micro-Mechanism of Initiation of Polynitro Arenes" . "S" . "[A570F14CB677]" . . . . . "Polarography in the Study of Chemical Micro-Mechanism of Initiation of Polynitro Arenes"@en . "Polarography in the Study of Chemical Micro-Mechanism of Initiation of Polynitro Arenes" . "P\u016Flvlnn\u00FD potenci\u00E1l dvaceti \u010Dty\u0159i polynitro arenes byl stanoven\u00FD ve vodn\u00FDch prost\u0159ed\u00EDch pufrovan\u00FDch na pH 7, pro dv\u011B koncentrace. Nalezen\u00E9 logick\u00E9 vztahy mezi t\u011Bmito potenci\u00E1ly a \u010Dtverci detona\u010Dn\u00EDch rychlosti jsou jedn\u00EDm z forem modifikovan\u00E9 Evans?Polanyi?Semenovovy rovnice pro energetick\u00E9 materi\u00E1ly. Siln\u00E1 z\u00E1vislost hodnoty potenci\u00E1l\u016F na podm\u00EDnk\u00E1ch a zp\u016Fsobu polarografick\u00FDch m\u011B\u0159en\u00ED zna\u010Dn\u011B omezujr pou\u017Eit\u00ED polarografie ve studiu mikro-mechanismu uveden\u00ED organick\u00FDch materi\u00E1l\u016F"@cs . "Polarography; Chemical Micro-Mechanism of Initiation; Polynitro Arenes"@en . "N" . . "Polarography in the Study of Chemical Micro-Mechanism of Initiation of Polynitro Arenes"@en . . "Zemanov\u00E1, Eva" . "The half-wave potentials, E1/2, of twenty four polynitro arenes have been determined in aqueous medium buffered at pH 7, the final concentrations of their solutions being 0.5x10?4 M and 0.5x10?5 M. The found logical relationships between the E1/2 values and squares of detonation velocity are of the type of the modified Evans?Polanyi?Semenov equation for energetic materials. It has been stated that the strong dependence of E1/2 values on the conditions and way of realisation of the polarographic measurements considerably restrict the application of this method to studies of micro-mechanism of initiation of organic energetic materials." . . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "The half-wave potentials, E1/2, of twenty four polynitro arenes have been determined in aqueous medium buffered at pH 7, the final concentrations of their solutions being 0.5x10?4 M and 0.5x10?5 M. The found logical relationships between the E1/2 values and squares of detonation velocity are of the type of the modified Evans?Polanyi?Semenov equation for energetic materials. It has been stated that the strong dependence of E1/2 values on the conditions and way of realisation of the polarographic measurements considerably restrict the application of this method to studies of micro-mechanism of initiation of organic energetic materials."@en . "Zeman, Svatopluk" . . "0737-0652" . . . "Journal of Energetic Materials" . "22" .