. . . . "Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface"@en . . . "50" . "Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface" . "High-resolution FT-IR spectroscopy combined with quantum chemical calculations was used to study the chemistry of OCS-disproportionation over the reduced surface of isotopically labelled, nanocrystalline TiO2. Analysis of the isotopic composition of the product gases has revealed that the reaction involves solely OCS molecules fromthe gas-phase. Using quantumchemical calculations we propose a plausible mechanistic scenario, in which two reduced Ti3+ centres mediate the reaction of the adsorbed OCS molecules." . "4"^^ . . "10.1039/c4cc01992j" . . "I, P(LD13060), P(LD14115)" . . "High-resolution FT-IR spectroscopy combined with quantum chemical calculations was used to study the chemistry of OCS-disproportionation over the reduced surface of isotopically labelled, nanocrystalline TiO2. Analysis of the isotopic composition of the product gases has revealed that the reaction involves solely OCS molecules fromthe gas-phase. Using quantumchemical calculations we propose a plausible mechanistic scenario, in which two reduced Ti3+ centres mediate the reaction of the adsorbed OCS molecules."@en . "Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface" . "6"^^ . . "TITANIUM-DIOXIDE; OXYGEN-EXCHANGE; CARBON-MONOXIDE; HYDROCARBONS; CHEMISTRY; TIO2(101); OXIDATION; ISOTOPE; METAL; FTIR"@en . "Zukalov\u00E1, Mark\u00E9ta" . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . "Kavan, Ladislav" . . . . "43274" . . "2"^^ . . "[F3F52B64A2C8]" . . "1359-7345" . . "RIV/00216224:14740/14:00076814" . . "RIV/00216224:14740/14:00076814!RIV15-MSM-14740___" . "http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01992j#!divAbstract" . "\u0160poner, Ji\u0159\u00ED" . "57" . . "\u0160ponerov\u00E1, Judit" . "Ferus, Martin" . . . "Chemical Communications" . . "000338234000038" . . "Civi\u0161, Svatopluk" . "Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface"@en . . . "14740" .