"RIV/00216224:14310/14:00080230" . . "Bystricky, R." . . "14310" . . "\u017D\u00E1k, Zdirad" . "Two novel heterometallic complexes [Cd(NH3)(6)][{VO-(O-2)(2)(OH)}(2){mu-Cd(NH3)(4)}] (2) and [{VO(O-2)(2)(Im)}(2){mu-Cu(Im)(4)}] (3) (Im = imidazole) containing peroxidovanadium complexes as metalloligands were prepared and characterized by spectral methods. X-ray single-crystal analysis revealed the presence of unique trinuclear complexes in the crystal structures of 2 and 3. The structure of 2 contains an anionic complex, whose two {VO(O-2)(2)(OH)}(2-) ions are interconnected by a {mu-Cd(NH3)(4)}(2+) group. Compound 3 is a trinuclear neutral complex comprising two {VO(O-2)(2)(Im)}(-) ions and a single bridging {mu-Cu(Im)(4)}(2+) group. The bonding via an equatorial OH- ligand in 2 and via a doubly bonded apical oxygen atom in 3 represents coordination modes previously unobserved for diperoxidovanadium complexes."@en . "7"^^ . . . "Gyepes, R." . "Antal, P." . . . "Tatiersky, J." . "I" . . "53" . "[359AA2BA0F23]" . "36244" . "000336240400030" . . . . "Peroxido Complexes of Vanadium(V) as Ligands. Crystal Structures of [Cd(NH3)(6)] [{VO(O-2)(2)(OH)}(2){mu-Cd(NH3)(4)}] and [{VO(O-2)(2)(Im)}(2){mu-Cu(Im)(4)}] (Im = Imidazole)" . "6"^^ . . . "Peroxido Complexes of Vanadium(V) as Ligands. Crystal Structures of [Cd(NH3)(6)] [{VO(O-2)(2)(OH)}(2){mu-Cd(NH3)(4)}] and [{VO(O-2)(2)(Im)}(2){mu-Cu(Im)(4)}] (Im = Imidazole)" . "Peroxido Complexes of Vanadium(V) as Ligands. Crystal Structures of [Cd(NH3)(6)] [{VO(O-2)(2)(OH)}(2){mu-Cd(NH3)(4)}] and [{VO(O-2)(2)(Im)}(2){mu-Cu(Im)(4)}] (Im = Imidazole)"@en . . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "KEGGIN STRUCTURE; HYDROGEN-PEROXIDE; DECAVANADATE ION; SOLID-STATE; OXIDATION; COMPOUND; POLYOXOMETALATE; BIOCHEMISTRY; SPECIATION; REACTIVITY"@en . "10.1021/ic500066p" . "Schwendt, Petr" . "1"^^ . . . "Peroxido Complexes of Vanadium(V) as Ligands. Crystal Structures of [Cd(NH3)(6)] [{VO(O-2)(2)(OH)}(2){mu-Cd(NH3)(4)}] and [{VO(O-2)(2)(Im)}(2){mu-Cu(Im)(4)}] (Im = Imidazole)"@en . . . "0020-1669" . "10" . . "Two novel heterometallic complexes [Cd(NH3)(6)][{VO-(O-2)(2)(OH)}(2){mu-Cd(NH3)(4)}] (2) and [{VO(O-2)(2)(Im)}(2){mu-Cu(Im)(4)}] (3) (Im = imidazole) containing peroxidovanadium complexes as metalloligands were prepared and characterized by spectral methods. X-ray single-crystal analysis revealed the presence of unique trinuclear complexes in the crystal structures of 2 and 3. The structure of 2 contains an anionic complex, whose two {VO(O-2)(2)(OH)}(2-) ions are interconnected by a {mu-Cd(NH3)(4)}(2+) group. Compound 3 is a trinuclear neutral complex comprising two {VO(O-2)(2)(Im)}(-) ions and a single bridging {mu-Cu(Im)(4)}(2+) group. The bonding via an equatorial OH- ligand in 2 and via a doubly bonded apical oxygen atom in 3 represents coordination modes previously unobserved for diperoxidovanadium complexes." . "RIV/00216224:14310/14:00080230!RIV15-MSM-14310___" . . . "Inorganic Chemistry" .