"Pot\u011B\u0161il, David" . . . "Mikelov\u00E1, Radka" . . . "Jelen, Franti\u0161ek" . . . . . "466309" . . "Attomole voltammetric determination of metallothionein" . "24" . . "Number of authors have concerned with electrochemical analysis of metallothionein. Recently new electroanalytical techniques enabling determination of MT at picomole level has been suggested. The aim of the presented work was to show advantages and disadvantages of the different electrochemical procedures, which are commonly used for the detection of MT(i) cyclic voltammetry, (ii) differential pulse voltammetry, and (iii) Brdicka reaction. Primarily we aimed on improvement of the mentioned techniques. Using of reducing agent (tris(2-carboxyethyl)phosphine) and combination of the mentioned method with adsorptive transfer stripping technique (AdTS) were the main improvements of the voltammetric method. The detection limits of metallothionein measured by cyclic voltammetry (CV), differential pulse voltammetry (DPV) and DPV Brdicka reaction were 0.5 pmol, 4 fmol and 10 amol, respectively." . . . "0013-4686" . . . "Attomole voltammetric determination of metallothionein" . . . "[A89A1831BA46]" . "Number of authors have concerned with electrochemical analysis of metallothionein. Recently new electroanalytical techniques enabling determination of MT at picomole level has been suggested. The aim of the presented work was to show advantages and disadvantages of the different electrochemical procedures, which are commonly used for the detection of MT(i) cyclic voltammetry, (ii) differential pulse voltammetry, and (iii) Brdicka reaction. Primarily we aimed on improvement of the mentioned techniques. Using of reducing agent (tris(2-carboxyethyl)phosphine) and combination of the mentioned method with adsorptive transfer stripping technique (AdTS) were the main improvements of the voltammetric method. The detection limits of metallothionein measured by cyclic voltammetry (CV), differential pulse voltammetry (DPV) and DPV Brdicka reaction were 0.5 pmol, 4 fmol and 10 amol, respectively."@en . . "10"^^ . "RIV/00216224:14310/06:00015758!RIV10-MSM-14310___" . . . "P(GP525/04/P132), V, Z(AV0Z50040507), Z(MSM0021622412)" . . "RIV/00216224:14310/06:00015758" . "Kuka\u010Dka, Ji\u0159\u00ED" . "6"^^ . . "Petrlov\u00E1, Jitka" . "Attomole voltammetric determination of metallothionein"@en . "Trnkov\u00E1, Libu\u0161e" . "Kizek, Ren\u00E9" . "51" . . "Bla\u0161t\u00EDk, Ond\u0159ej" . . "Metallothionein; Mercury electrode; Differential pulse voltammetry; Cyclic voltammetry; Brdicka reaction; Adsorptive transfer stripping technique; Reducing agent; Tris(2-carboxyethyl)phosphine; Lead poisoning; Human blood serum"@en . . . . . "Electrochimica Acta" . "Attomole voltammetric determination of metallothionein"@en . . . . . "Pr\u016F\u0161a, Richard" . "Adam, Vojt\u011Bch" . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . "8"^^ . "14310" .