"Ori\u0148\u00E1kov\u00E1, Ren\u00E1ta" . "524641" . . . . . . "Ni electrodeposition; chloride supporting electrolyte; graphite electrode; boric acid; elimination voltammetry"@en . . "The electrolytic deposition of Ni onto a paraffin-impregnated graphite electrode from supporting chloride electrolyte (0.5 mol dm(-3) NaCl) adjusted to the required pH using dilute HCl is investigated. The effect of electrolyte composition on the Ni electrodeposition is studied using linear sweep voltammetry in the cathodic region. An elimination voltammetry procedure was applied to evaluate the polarization curves. The aim of this work was to deduce the mechanism of Ni reduction in the chloride bath as well as the influence of boric acid on this. Positively-charged NiCl+ ions were found to be the electroactive particles in the Ni reduction mechanism. The strong competition between the NiCl+, Cl- and H+ ions for active sites at the electrode is discussed. Kinetically-controlled adsorption/desorption processes of various species were also confirmed using elimination voltammetry with a linear scan." . "RIV/00216224:14310/05:00014662!RIV10-MSM-14310___" . "Trnkov\u00E1, Libu\u0161e" . "\u0160upicov\u00E1, Magdalena" . "10" . "Z(MSM0021622412)" . "2"^^ . . . . . "[33E175CC6E8A]" . "G\u00E1lov\u00E1, Miriam" . . "8"^^ . "1432-8488" . "2" . . "5"^^ . . . "Influence of boric acid on the electrochemical deposition of Ni"@en . . "14310" . "CZ - \u010Cesk\u00E1 republika" . "Influence of boric acid on the electrochemical deposition of Ni"@en . "JOURNAL OF SOLID STATE ELECTROCHEMISTRY" . "The electrolytic deposition of Ni onto a paraffin-impregnated graphite electrode from supporting chloride electrolyte (0.5 mol dm(-3) NaCl) adjusted to the required pH using dilute HCl is investigated. The effect of electrolyte composition on the Ni electrodeposition is studied using linear sweep voltammetry in the cathodic region. An elimination voltammetry procedure was applied to evaluate the polarization curves. The aim of this work was to deduce the mechanism of Ni reduction in the chloride bath as well as the influence of boric acid on this. Positively-charged NiCl+ ions were found to be the electroactive particles in the Ni reduction mechanism. The strong competition between the NiCl+, Cl- and H+ ions for active sites at the electrode is discussed. Kinetically-controlled adsorption/desorption processes of various species were also confirmed using elimination voltammetry with a linear scan."@en . "Influence of boric acid on the electrochemical deposition of Ni" . . . "RIV/00216224:14310/05:00014662" . "Influence of boric acid on the electrochemical deposition of Ni" . "Rozik, Roland" . .