"The paper describes successful coupling of adsorptive transfer stripping (AdTS) and elimination voltammetry with linear scan (EVLS) for the resolution of reduction signals of cytosine ( C) and adenine ( A) residues in hetero-oligodeoxynucleotides (ODNs). Short ODNs (9-mers and 20-mers) were adsorbed from a small volume on a hanging mercury drop electrode (HMDE). After washing of the ODN-modified electrode by water and its transferring to an electrochemical cell, voltammetric curves were measured. The AdTS EVLS was able to determine of C/A ratio of ODNs through the elimination function conserving the diffusion current component and eliminating kinetic and charging current components. This function, which provides the elimination signal in a peak-counterpeak form, increased the current sensitivity for A and C resolution, and for the recognition of bases sequences in ODN chains. Optimal conditions of elimination experiments such as pH, time of adsorption, and scan rate were found."@en . . . "RIV/00216224:14310/05:00014629" . . . "6"^^ . "oligodeoxynucleotide; DNA biosensor; linear sweep voltammetry; elimination voltammetry with linear scan; reduction of adenine and cytosine; mercury electrode; sequence of nucleotides"@en . "5"^^ . "Adam, Vojt\u011Bch" . . . "The paper describes successful coupling of adsorptive transfer stripping (AdTS) and elimination voltammetry with linear scan (EVLS) for the resolution of reduction signals of cytosine ( C) and adenine ( A) residues in hetero-oligodeoxynucleotides (ODNs). Short ODNs (9-mers and 20-mers) were adsorbed from a small volume on a hanging mercury drop electrode (HMDE). After washing of the ODN-modified electrode by water and its transferring to an electrochemical cell, voltammetric curves were measured. The AdTS EVLS was able to determine of C/A ratio of ODNs through the elimination function conserving the diffusion current component and eliminating kinetic and charging current components. This function, which provides the elimination signal in a peak-counterpeak form, increased the current sensitivity for A and C resolution, and for the recognition of bases sequences in ODN chains. Optimal conditions of elimination experiments such as pH, time of adsorption, and scan rate were found." . "14310" . . "Kizek, Ren\u00E9" . . . . . . "Trnkov\u00E1, Libu\u0161e" . "5" . . "Elimination voltammetry with linear scan as a new detection method for DNA sensors" . . "Jelen, Franti\u0161ek" . "P(1H-PK/42), P(GP525/04/P132), Z(AV0Z50040507), Z(MSM0021622412)" . . "Pot\u011B\u0161il, David" . . . . "SENSORS" . "RIV/00216224:14310/05:00014629!RIV10-MSM-14310___" . "Elimination voltammetry with linear scan as a new detection method for DNA sensors"@en . . "1424-8220" . . . "Elimination voltammetry with linear scan as a new detection method for DNA sensors" . . . "CZ - \u010Cesk\u00E1 republika" . . . . "17"^^ . "[F9B2A8F6B28A]" . "6-10" . "Elimination voltammetry with linear scan as a new detection method for DNA sensors"@en . "520102" . "Petrlov\u00E1, Jitka" . .