. . . "P\u0159\u00EDprava a charakterizace nov\u00FDch deriv\u00E1t\u016F alumazenu"@cs . "L\u00F6bl, Ji\u0159\u00ED" . "P\u0159\u00EDprava a charakterizace nov\u00FDch deriv\u00E1t\u016F alumazenu" . "2"^^ . "538522" . "P(GA203/04/0296), Z(MSM0021622410)" . "14310" . "Pinkas, Ji\u0159\u00ED" . . "Synthesis and characterization of new alumazene derivatives"@en . "Vysok\u00E9 Tatry, SK" . . . . "1,3,5-trimethyl-2,4,6-tris(2,6-diisopropylfenyl)alumazen je dosud jedin\u00FD zn\u00E1m\u00FD z\u00E1stupce trimern\u00EDch poly(N-alkyliminoalan\u016F). P\u0159ipravuje se reakc\u00ED trimethylalanu s 2,6-diisopropylanilinem. S c\u00EDlem p\u0159ipravit nov\u00E9 cyklick\u00E9 a polyedrick\u00E9 organoaluminofosfon\u00E1ty jsme studovali reakce alumazenu s trimethylsilylestery fosfonov\u00FDch kyselin. Reakc\u00ED alumazenu s bis(trimethylsilyl)esterem kyseliny methylfosfonov\u00E9 jsme dealkylsilyla\u010Dn\u00ED reakc\u00ED p\u0159ipravili bicyklick\u00FD aluminofosfon\u00E1t. Obdobn\u00FD produkt jsme z\u00EDskali reakc\u00ED alumazenu s bis(trimethylsilyl)esterem kyseliny fenylfosfonov\u00E9, ale tyto dv\u011B slou\u010Deniny jsou strukturn\u011B odli\u0161n\u00E9 v poloze substituent\u016F m\u016Fstkov\u00E9 fosfon\u00E1tov\u00E9 skupiny nad kruhem alumazenu. Zcela jinak prob\u00EDh\u00E1 reakce alumazenu s bis(trimethylsilyl)esterem kyseliny trichlormethylfosfonov\u00E9. Produktem t\u00E9to dealkylsilyla\u010Dn\u00ED reakce je spiroslou\u010Denina, u kter\u00E9 do\u0161lo k p\u0159euspo\u0159\u00E1d\u00E1n\u00ED kruhu alumazenu a inzerci fosfon\u00E1tu do cyklu. P\u0159i reakci alumazenu s trifenylfosfinoxidem doch\u00E1z\u00ED ke vzniku bisaduktu." . "1336-7242" . . "1"^^ . . "alumazene; iminoalanes; dealkylsilylation"@en . "2005-01-01+01:00"^^ . . "[DC6B6EC210D7]" . . "Synthesis and characterization of new alumazene derivatives"@en . "RIV/00216224:14310/05:00012611" . "Results in the synthesis and characterization of 1,3,5-trimethyl-2,4,6-tris(2,6-diisopropylphenyl)alumazene derivatives and studies of the reactions of alumazene with trimethylsilylesters of phosphonic acids. The reactions of alumazene with bis(trimethylsilyl)ester methylphosphonic aacids lead by dealkylsilylation to a bicyclic aluminophosphonate."@en . . "P\u0159\u00EDprava a charakterizace nov\u00FDch deriv\u00E1t\u016F alumazenu" . "SCHS" . . . "P\u0159\u00EDprava a charakterizace nov\u00FDch deriv\u00E1t\u016F alumazenu"@cs . . "ChemZi" . . . . . "1,3,5-trimethyl-2,4,6-tris(2,6-diisopropylfenyl)alumazen je dosud jedin\u00FD zn\u00E1m\u00FD z\u00E1stupce trimern\u00EDch poly(N-alkyliminoalan\u016F). P\u0159ipravuje se reakc\u00ED trimethylalanu s 2,6-diisopropylanilinem. S c\u00EDlem p\u0159ipravit nov\u00E9 cyklick\u00E9 a polyedrick\u00E9 organoaluminofosfon\u00E1ty jsme studovali reakce alumazenu s trimethylsilylestery fosfonov\u00FDch kyselin. Reakc\u00ED alumazenu s bis(trimethylsilyl)esterem kyseliny methylfosfonov\u00E9 jsme dealkylsilyla\u010Dn\u00ED reakc\u00ED p\u0159ipravili bicyklick\u00FD aluminofosfon\u00E1t. Obdobn\u00FD produkt jsme z\u00EDskali reakc\u00ED alumazenu s bis(trimethylsilyl)esterem kyseliny fenylfosfonov\u00E9, ale tyto dv\u011B slou\u010Deniny jsou strukturn\u011B odli\u0161n\u00E9 v poloze substituent\u016F m\u016Fstkov\u00E9 fosfon\u00E1tov\u00E9 skupiny nad kruhem alumazenu. Zcela jinak prob\u00EDh\u00E1 reakce alumazenu s bis(trimethylsilyl)esterem kyseliny trichlormethylfosfonov\u00E9. Produktem t\u00E9to dealkylsilyla\u010Dn\u00ED reakce je spiroslou\u010Denina, u kter\u00E9 do\u0161lo k p\u0159euspo\u0159\u00E1d\u00E1n\u00ED kruhu alumazenu a inzerci fosfon\u00E1tu do cyklu. P\u0159i reakci alumazenu s trifenylfosfinoxidem doch\u00E1z\u00ED ke vzniku bisaduktu."@cs . "Bratislava, SK" . "2"^^ . "RIV/00216224:14310/05:00012611!RIV10-MSM-14310___" .