. "Masarykova univerzita v Brn\u011B" . "Cations; donor-acceptor complexes; N-ligands; dioxophosphonium; crystal structures"@en . "Donor-Stabilized Dioxophosphonium Cation: Synthesis, Hydrolysis and Crystal Structure of [(DMAP)2PO2]Cl.CH3CN" . "RIV/00216224:14310/02:00007355!RIV08-MSM-14310___" . "[1D9495B831D6]" . "RIV/00216224:14310/02:00007355" . "58" . "Donor-Stabilized Dioxophosphonium Cation: Synthesis, Hydrolysis and Crystal Structure of [(DMAP)2PO2]Cl.CH3CN"@cs . . . "80-210-2951-X" . "Donor-Stabilized Dioxophosphonium Cation: Synthesis, Hydrolysis and Crystal Structure of [(DMAP)2PO2]Cl.CH3CN"@en . . . "2"^^ . "14310" . "2002-01-01+01:00"^^ . "16.-19. 9. 2002, Vranov u Brna" . . . . . "Donor-Stabilized Dioxophosphonium Cation: Synthesis, Hydrolysis and Crystal Structure of [(DMAP)2PO2]Cl.CH3CN"@cs . "643587" . . "Sborn\u00EDk p\u0159\u00EDsp\u011Bvk\u016F IV. semin\u00E1\u0159 Pokroky v anorganick\u00E9 chemii" . . . "Rovnan\u00EDk, Pavel" . "\u010Cern\u00EDk, Milo\u0161" . "Z(MSM 143100011)" . . "Donor-Stabilized Dioxophosphonium Cation: Synthesis, Hydrolysis and Crystal Structure of [(DMAP)2PO2]Cl.CH3CN" . . "2"^^ . . . "The reaction of POCl3 with strong basic 4-dimethylaminopyridine /DMAP/ in liquid SO2 produces a white solid that could be recrystallized from acetonitrile. The single-crystal structure determination revealed an ionic structure of bis(4-dimethylaminopyridine)dioxophosphonium chloride solvated by one molecule of acetonitrile.It can be considered a salt of donor-stabilised PO2+ ion,an hitherto unknown analogue of the nitronium cation,NO2+. A 31P NMR spectroscopic study showed a significant difference between the acid and alkali hydrolysis of [(DMAP)2PO2]+ ion and enabled to propose the corresponding reaction mechanism." . "Brno" . . "Donor-Stabilized Dioxophosphonium Cation: Synthesis, Hydrolysis and Crystal Structure of [(DMAP)2PO2]Cl.CH3CN"@en . "2"^^ . "The reaction of POCl3 with strong basic 4-dimethylaminopyridine /DMAP/ in liquid SO2 produces a white solid that could be recrystallized from acetonitrile. The single-crystal structure determination revealed an ionic structure of bis(4-dimethylaminopyridine)dioxophosphonium chloride solvated by one molecule of acetonitrile.It can be considered a salt of donor-stabilised PO2+ ion,an hitherto unknown analogue of the nitronium cation,NO2+. A 31P NMR spectroscopic study showed a significant difference between the acid and alkali hydrolysis of [(DMAP)2PO2]+ ion and enabled to propose the corresponding reaction mechanism."@cs . "The reaction of POCl3 with strong basic 4-dimethylaminopyridine /DMAP/ in liquid SO2 produces a white solid that could be recrystallized from acetonitrile. The single-crystal structure determination revealed an ionic structure of bis(4-dimethylaminopyridine)dioxophosphonium chloride solvated by one molecule of acetonitrile.It can be considered a salt of donor-stabilised PO2+ ion,an hitherto unknown analogue of the nitronium cation,NO2+. A 31P NMR spectroscopic study showed a significant difference between the acid and alkali hydrolysis of [(DMAP)2PO2]+ ion and enabled to propose the corresponding reaction mechanism."@en . . .