. "6"^^ . "[76232F4CA422]" . . "Sunlight photolysis of decamethyltitanocene dihydrosulfide [Cp*2Ti(SH)2] (1, Cp* = 5-C5Me5) in toluene affords the titanium sulfide clusters [(Cp*Ti)6(3-S)8] (4) and [(Cp*Ti)4(3-S)3(2-S)3] (5), the former in very low yield and the latter in good yield. The crystal structures of both compounds are toluene solvates and are based on a nearly regular titanium octahedron for 4 and a trigonal pyramid for 5. The [(Cp*Ti)3(3-S)(2-S)3] (6) complex isolated in a trace amount from the photolysis of 1 in hexane could be a precursor of 4. A plausible mechanism for the formation of 5 and 6 follows a mechanism recently proposed for photolysis of [Cp*2Ti(OH)2] by U. Rosenthal et al." . . . "http://dx.doi.org/10.1002/ejic.201300391" . "C\u00EDsa\u0159ov\u00E1, Ivana" . "108995" . . "Kubi\u0161ta, Ji\u0159\u00ED" . . "RIV/00216208:11310/13:10141574" . "neuveden" . . "1"^^ . . . "11310" . "Mach, Karel" . "19" . . "7"^^ . "Hor\u00E1\u010Dek, Michal" . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . "I, P(GAP207/12/2368), Z(MSM0021620857)" . "Sunlight Photolysis of Decamethyltitanocene Dihydrosulfide Affords the Titanium Sulfide Cage Clusters (Cp*Ti)6S8 and (Cp*Ti)4S6"@en . "Pinkas, Ji\u0159\u00ED" . "Sunlight Photolysis of Decamethyltitanocene Dihydrosulfide Affords the Titanium Sulfide Cage Clusters (Cp*Ti)6S8 and (Cp*Ti)4S6"@en . "10.1002/ejic.201300391" . . "Sunlight Photolysis of Decamethyltitanocene Dihydrosulfide Affords the Titanium Sulfide Cage Clusters (Cp*Ti)6S8 and (Cp*Ti)4S6" . "Gyepes, R\u00F3bert" . . "Sunlight Photolysis of Decamethyltitanocene Dihydrosulfide Affords the Titanium Sulfide Cage Clusters (Cp*Ti)6S8 and (Cp*Ti)4S6" . "000320783300007" . "RIV/00216208:11310/13:10141574!RIV14-MSM-11310___" . . "sulfur; titanium; cluster compounds; cage compounds; metallocenes; photolysis"@en . . . . "European Journal of Inorganic Chemistry" . . . . . . "Sunlight photolysis of decamethyltitanocene dihydrosulfide [Cp*2Ti(SH)2] (1, Cp* = 5-C5Me5) in toluene affords the titanium sulfide clusters [(Cp*Ti)6(3-S)8] (4) and [(Cp*Ti)4(3-S)3(2-S)3] (5), the former in very low yield and the latter in good yield. The crystal structures of both compounds are toluene solvates and are based on a nearly regular titanium octahedron for 4 and a trigonal pyramid for 5. The [(Cp*Ti)3(3-S)(2-S)3] (6) complex isolated in a trace amount from the photolysis of 1 in hexane could be a precursor of 4. A plausible mechanism for the formation of 5 and 6 follows a mechanism recently proposed for photolysis of [Cp*2Ti(OH)2] by U. Rosenthal et al."@en . "1434-1948" . .