"Organometallics" . "1"^^ . "Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives"@en . "0276-7333" . "000266156900023" . "The reactions of a C,N-chelated ((L-CN)(2)M, where L-CN is 2-((dimethylamino)methyl)phenyl and M is Sn (1) or Pb (2)) stannylene and plumbylene with di-n-butylbis(eta(5)-cyclopentadienyl)zirconium (3) were studied. In the case of the stannylene, the trinuclear carbene-like complex [(L-CN)(2)Sn](2)CP2Zr (4) was isolated as the major product. The second product isolated resultedfirom transmetalation of the CN-chelating ligand from tin to zirconium, followed by 1-butene coupling to the coordinated aryne (C,N-chelating ligand) (5). In the lead case, the major product was the complex 5. Byproducts were elemental lead, thefiree ligand ((LH)-H-CN), butane, and 1-butene. The oxidation of 4 by oxygen gave the six- trioxatrizircona cyclic complex (6) and an eight-membered tetraoxa tetrastanna cyclic complex (7)."@en . . "The reactions of a C,N-chelated ((L-CN)(2)M, where L-CN is 2-((dimethylamino)methyl)phenyl and M is Sn (1) or Pb (2)) stannylene and plumbylene with di-n-butylbis(eta(5)-cyclopentadienyl)zirconium (3) were studied. In the case of the stannylene, the trinuclear carbene-like complex [(L-CN)(2)Sn](2)CP2Zr (4) was isolated as the major product. The second product isolated resultedfirom transmetalation of the CN-chelating ligand from tin to zirconium, followed by 1-butene coupling to the coordinated aryne (C,N-chelating ligand) (5). In the lead case, the major product was the complex 5. Byproducts were elemental lead, thefiree ligand ((LH)-H-CN), butane, and 1-butene. The oxidation of 4 by oxygen gave the six- trioxatrizircona cyclic complex (6) and an eight-membered tetraoxa tetrastanna cyclic complex (7)." . "7"^^ . "4"^^ . . "C\u00EDsa\u0159ov\u00E1, Ivana" . . "RIV/00216208:11310/09:10001113" . . "[96DCB0F1FE62]" . . . "Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives" . "Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives"@en . "RIV/00216208:11310/09:10001113!RIV10-GA0-11310___" . . "338196" . "Pad\u011Blkov\u00E1, Zde\u0148ka" . "Bare\u0161, Josef" . . "28" . . . "R\u016F\u017Ei\u010Dka, Ale\u0161" . . "P(GA203/07/0468), P(KJB401550802), Z(MSM0021627501)" . . . "Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives" . . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "\u010Cerno\u0161ek, Zden\u011Bk" . . "Philippe, Philippe" . . "CNchelatedTin(II); Lead(II)Compounds; ZirconoceneDichlorideDerivatives"@en . . . "11310" . "Pirio, Nadine" . "10" .