. "4"^^ . "000267728200012" . . . . . "8"^^ . "RIV/00216208:11310/09:10000304!RIV11-MSM-11310___" . "33" . . . "stereochemistry; ligands; mandelic-acid; peroxo complexes; peroxovanadium complexes; supramolecular interactions; vanadium(v) oxo; coordination polymers; crystal-structure; Oxo-monoperoxo complexes"@en . . "1"^^ . "Two new neutral monoperoxidovanadium(V) complexes [VO(O-2)(L)(pa)]center dot xH(2)O have been synthesized: [VO(O-2)(pic)(pa)]center dot H2O (1) and [VO(O-2)(Hquin)(pa)]center dot 2H(2)O (2) [pic: pyridine-2-carboxylato(1-) or picolinato(1-), Hquin: pyridine-2,3-dicarboxylato(1-) or quinolinato(1-), and pa: picolinamide]. The solid state structures of 1 and 2 feature a typical distorted pentagonal bipyramid coordination polyhedron around the central vanadium atoms. The bidentate anionic ligands are coordinated in two equatorial positions, while the bidentate picolinamide molecule is bound via the aromatic nitrogen and the carboxamide oxygen in one equatorial and one apical position." . "[8EAD0648BCBF]" . "Two new neutral monoperoxidovanadium(V) complexes [VO(O-2)(L)(pa)]center dot xH(2)O have been synthesized: [VO(O-2)(pic)(pa)]center dot H2O (1) and [VO(O-2)(Hquin)(pa)]center dot 2H(2)O (2) [pic: pyridine-2-carboxylato(1-) or picolinato(1-), Hquin: pyridine-2,3-dicarboxylato(1-) or quinolinato(1-), and pa: picolinamide]. The solid state structures of 1 and 2 feature a typical distorted pentagonal bipyramid coordination polyhedron around the central vanadium atoms. The bidentate anionic ligands are coordinated in two equatorial positions, while the bidentate picolinamide molecule is bound via the aromatic nitrogen and the carboxamide oxygen in one equatorial and one apical position."@en . "1144-0546" . . . . . . "Siv\u00E1k, Michal" . "Tatiersky, Jozef" . "314187" . . "Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide)" . . . . "Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide)"@en . "Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide)" . . "11310" . . "New Journal of Chemistry" . . . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . . "Z(MSM0021620857)" . "2009" . "Pacigov\u00E1, Silvia" . "RIV/00216208:11310/09:10000304" . "Gyepes, R\u00F3bert" . "Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide)"@en .