"Z\u00E1kladn\u00ED c\u00EDlen\u00FD v\u00FDzkum, anorganick\u00E9, organometalick\u00E9 a organometaloidn\u00ED slou\u010Deniny a perspektivn\u00ED materi\u00E1ly (amorfn\u00ED, sklovit\u00E9 a krystalick\u00E9) s potenci\u00E1ln\u00EDm vyu\u017Eit\u00EDm v chemii, katal\u00FDze, elektronice, optice, optoelektronice a ve zdravotnictv\u00ED.Amorfn\u00ED a sklovit\u00E9 chalkogenidy a oxidy, p\u0159\u00EDprava, metoda sol-gel, tenk\u00E9 vrstvy, nano\u010D\u00E1stice, napra\u0161ov\u00E1n\u00ED, optick\u00E9, termick\u00E9 a chemick\u00E9 vlastnosti, struktura, reaktivita, luminiscence, katalytick\u00E9 a fotoindukovan\u00E9 jevy, z\u00E1pis informac\u00EDBude rozv\u00EDjena chemie nov\u00FDch metalocen\u016F a organokovov\u00FDch slou\u010Denin Sn s d\u016Frazem na mono- a v\u00EDcejadern\u00E9 komplexy. Pomoc\u00ED modern\u00EDch metod budou sledov\u00E1ny vztahy mezi strukturou a statick\u00FDmi a dynamick\u00FDmi (reaktivita, katal. a biol. aktivita) vlastnostmi.Aplikac\u00ED inser\u010Dn\u00EDch a degrada\u010Dn\u00EDch reakc\u00ED B-skeletu budou hled\u00E1ny cesty p\u0159\u00EDpravy nov\u00FDch typ\u016F karboran\u016F, heteroboran\u016F a heterokarboran\u016F (obsahuj\u00EDc\u00EDch elementy skup. 15). Bude rozv\u00EDjena i jejich metalaboranov\u00E1 chemie s d\u016Frazem na analoga ferrocenu" . . . " nanoparticles" . " metallorganic compounds" . "Nov\u00E9 a perspektivn\u00ED anorganick\u00E9 slou\u010Deniny a materi\u00E1ly" . " oxides" . . . "Advanced materials; Inorganic compounds; Amorphous and glassy chalcogenides; oxides; semiconductors; metallorganic compounds; heteroboranes; carboranes; nanoparticles; structure; optical properties; magnetic properties; thermal properties; NMR"@en . "268"^^ . "268"^^ . "http://www.isvav.cz/projectDetail.do?rowId=LN00A028"^^ . "2008-05-28+02:00"^^ . . "Advanced materials" . . . . . . . " semiconductors" . "New inorganic compounds and advanced materials"@en . . "LN00A028" . "Fundamental oriented research, inorganic, organometallic, organometalloid compounds and advanced materials (amorphous, glassy, crystalline) with potential application in chemistry, catalysis, electronics, optics, optoelectronics and in pharmacy.Amorphous, glassy chalcogenides and oxides, preparation, sol-gel method, thin films, nanoparticles, sputtering, optical, thermal and chemical properties, structure, reactivity, luminescence, catalytic and photoinduced effects, informations storage.Developed will be chemistry of metallocenes and organometallic Sn compounds, with emphasis on mono- and multinuclear complexes. Via recent methods, relations between static and dynamic (reactivity, catal. and biol. activity) properties will be explored.Via insertion and degradation reactions of the B-cage, new ways to new carboranes and Group 15 heteroboranes and heterocarboranes will be explored. Their metallaborane chemistry with emphasis on ferrocene analogues will be developed as well."@en . "0"^^ . " thermal properties" . . " Inorganic compounds" . . "P\u0159ipraveny a prostudov\u00E1ny perspektivn\u00ED slou\u010Deniny a syst\u00E9my (amorfn\u00ED chalkogenidy, oxidy kov\u016F, nanomateri\u00E1ly, organometallick\u00E9 a organometalloidn\u00ED l\u00E1tky) s vyu\u017Eit\u00EDm v informa\u010Dn\u00EDch technologi\u00EDch, v katalyze, ve zdravotnictv\u00ED. Zv\u00FD\u0161ena mezin\u00E1rodn\u00ED spolupr\u00E1c"@cs . . . . " carboranes" . " magnetic properties" . " structure" . "1"^^ . . "1"^^ . . " heteroboranes" . "Advanced materials and compounds (amorphous chalcogenides, metallic oxides, nanomaterials, orgnometallics, organometalloids) with application in information technologies, in catalysis and medicine were prepared and studied. International and publications"@en . " Amorphous and glassy chalcogenides" . . " optical properties" . .