. . "fotochemie" . . "2016-12-31+01:00"^^ . "1"^^ . "Struktura a dynamika excitovan\u00FDch a redoxn\u00EDch stav\u016F fotokatalytick\u00FDch komplex\u016F" . "0"^^ . "2014-04-01+02:00"^^ . . . "0"^^ . . . . "LD14129" . " kvantov\u00E1 chemie" . "http://www.isvav.cz/projectDetail.do?rowId=LD14129"^^ . " excitovan\u00E9 stavy" . " sol\u00E1rn\u00ED energie" . " elektrochemie" . "6"^^ . . "6"^^ . " fotokatal\u00FDza" . "Structure and dynamics of excited and redox states of photocatalytic complexes"@en . "fotochemie; fotokatal\u00FDza; elektrochemie; kvantov\u00E1 chemie; p\u0159enos elektronu; excitovan\u00E9 stavy; sol\u00E1rn\u00ED energie; \u0161t\u011Bpen\u00ED vody"@en . . . . . . . "2015-04-29+02:00"^^ . "We will carry out a collaborative research in the framework of the COST Action CM1202 %22Supramolecular photocatalytic water splitting%22 that is aimed at fundamental understanding of processes involved in photocatalyzed splitting of water to hydrogen and oxygen and at the development of new functional systems. In particular, we will perform combined experimental and theoretical investigations in the following directions: 1) character, structure, and dynamics of excited states of new types of photosensitizers (e.g. push-pull metal dithiolenes, rhenium complexes, corroles); 2) dynamics of ultrafast photoinduced electron transfer and their control; and 3) electrochemistry, spectroelectrochemistry and electronic structure of new water reduction and oxidation (photo)catalysts, e.g. dinuclear organometallic Ru complexes with redox-active bridging ligands. Toward the end of the project, we will generalize our results and formulate design principles aiding development and optimization of supramolecular photocatalytic systems."@en . "2014-05-19+02:00"^^ . . . " p\u0159enos elektronu" . . "C\u00EDlem projektu je p\u0159isp\u011Bt k pozn\u00E1n\u00ED fotokatalytick\u00E9ho \u0161t\u011Bpen\u00ED vody a v\u00FDvoji funk\u010Dn\u00EDch syst\u00E9m\u016F (t.j. k c\u00EDl\u016Fm COST Akce CM1202) v n\u00E1sleduj\u00EDc\u00EDch sm\u011Brech: 1) studiem povahy, struktury a dynamiky excitovan\u00FDch stav\u016F nov\u00FDch typ\u016F fotosensitiz\u00E1tor\u016F (nap\u0159. push-pull dithiolenov\u00FDch komplex\u016F, rheniov\u00FDch komplex\u016F, corrol\u016F), 2) studiem dynamiky ultrarychl\u00E9ho fotoindukovan\u00E9ho p\u0159enosu elektronu a mechanism\u016F jeho kontroly, 3) studiem elektrochemie, spektroelektrochemie a elektronov\u00E9 struktury katalyz\u00E1tor\u016F redukce a oxidace vody (nap\u0159. dvojjadern\u00FDch Ru komplex\u016F s redox aktivn\u00EDmi m\u016Fstkuj\u00EDc\u00EDmi ligandy), 4) Zobecn\u011Bn\u00EDm z\u00EDskan\u00FDch v\u00FDsledk\u016F a formulac\u00ED princip\u016F pro konstrukci a optimalizaci supramolekul\u00E1rn\u00EDch fotokatalytick\u00FDch syst\u00E9m\u016F." . .