. "V projektu bude studov\u00E1n v\u00FDvoj nov\u00FDch cest pro p\u0159\u00EDpravu polyfluorovan\u00FDch slou\u010Denin, kter\u00E9 mohou b\u00FDt pou\u017Eity jako ligandy v komplexech p\u0159echodn\u00FDch kov\u016F s potenci\u00E1ln\u00EDm vyu\u017Eit\u00EDm fe fluorov\u00FDch dvouf\u00E1zov\u00FDch syst\u00E9mech. Z\u00E1kladn\u00EDmi stavebn\u00EDmi kameny pro synt\u00E9zu t\u011Bchto polyfluorovan\u00FDch slou\u010Denin budou alkiny s polyfluorovan\u00FDmi substituenty. Byly identifikov\u00E1ny \u010Dty\u0159i postupn\u00E9 c\u00EDle: 1) v\u00FDvoj obecn\u00E9ho postupu pro p\u0159\u00EDpravu alkin\u016F s polyfluorovan\u00FDmi substituenty, 2) studium t\u011Bchto alkin\u016F v reakc\u00EDch zprost\u0159edkovan\u00FDch nebo katalyzovan\u00FDch p\u0159echodn\u00FDmi kovy jako jsou r\u016Fzn\u00E9 cykloadi\u010Dn\u00ED reakce, 3) p\u0159\u00EDprava fluorovan\u00FDch cyklopentadien\u016F, fulven\u016F, heterocykl\u016F a arylfosfin\u016F, kter\u00E9 mohou b\u00FDt pou\u017Eity jako ligandy pro p\u0159echodn\u00E9 kovy, 4) p\u0159\u00EDprava komplex\u016F p\u0159echodn\u00FDch kov\u016F s t\u011Bmito ligandy a stanoven\u00ED jejich fluorofilicity a dal\u0161\u00EDch vlastnost\u00ED." . "Novel fluorophilic ligands for transition metal complexes based on polyfluorinated"@en . . . . . . "Nov\u00E9 fluorofiln\u00ED ligandy pro komplexy p\u0159echodn\u00FDch kov\u016F odvozen\u00E9 od polyfluorovan\u00FDch alkin\u016F" . " Fluorophilic ligands" . "Byla vypracov\u00E1na synt\u00E9za polyfluorovan\u00FDch alkyn\u016F a nalezeny cesty k z\u00EDsk\u00E1n\u00ED polyfluorovan\u00FDch cyklopentadien\u016F. Komplexy p\u0159echodn\u00FDch kov\u016F s polyfluorovan\u00FDmi \u0159et\u011Bzci byly z\u00EDsk\u00E1ny z existuj\u00EDc\u00EDch komplex\u016F a dvou dal\u0161\u00EDch typ\u016F polyfluorovan\u00FDch cyklopentadien\u016F."@cs . . . "http://www.isvav.cz/projectDetail.do?rowId=IAA4072203"^^ . "Development of ne\u0161 pathways for preparation of polyfluorinated compounds that could be used as ligands in transition metal complexes with a potential use in fluotous biphase systems will be studied in the proposal. The basic building blocks for the synthesis of the polyfluorinated compounds will be alkynes with polyfluorinated substituents. Four successive targets were identified: 1) development of a general procedure for the preparation of alkynes with polyfluorinated substituents, 2) study of these alkynes in transition-metal induced or catalyzed reactions such as various cycloaddition reactions, 3) preparation of fluorinated cyclopentadienes, fulvenes, heterocycels, and arylphosphines that could be used as ligands for transition metals, 4) preparation of transition metal complexes with those ligands and determination of their fluorophilicity and other properties."@en . . "0"^^ . "IAA4072203" . "Polyfluorinated alkynes; Cycloaddition; Fluorophilic ligands; Transition metal catalysts; Fluorous biphase catalysis"@en . "0"^^ . . "Polyfluorinated alkynes" . "Synthesis of polyfluorinated alkynes and ways of obtaining polufluorinated cyclopentadienes were found. Transition metal complexes with polyfluorinated chains were also prepared from the existing complexes and from two other types of cyclopentadienes."@en . "2007-09-26+02:00"^^ . "3"^^ . . . . " Cycloaddition" . "11"^^ . "11"^^ . . " Transition metal catalysts" . . . . . . .