. "0"^^ . "Hlavn\u00EDm c\u00EDlem \u0159e\u0161en\u00ED je charakterizovat kompaktn\u00ED prekurzory polymern\u00EDch s\u00EDt\u00ED a reaktivitu jejich funk\u010Dn\u00EDch skupin, objasnit zvl\u00E1\u0161tnosti jejich chemick\u00E9ho spojov\u00E1n\u00ED do makros\u00EDt\u00ED a charakterizovat strukturu a vlastnosti t\u011Bchto makros\u00EDt\u00ED v\u010Detn\u011B jejich potenci\u00E1ln\u00EDch aplikac\u00ED. D\u016Fle\u017Eit\u00FDm c\u00EDlem tohoto projektu je tak\u00E9 teoretick\u00FD popis uveden\u00FDch syst\u00E9m\u016F a pochod\u016F. V projektu uva\u017Eovan\u00E9 prekurzory zahrnuj\u00ED hyperv\u011Btven\u00E9 polymery vznikl\u00E9 polyreakcemi BAf, reaktivn\u00ED mikrogely p\u0159ipraven\u00E9 emulzn\u00ED polymerizac\u00ED a mechanochemicky z\u00FA\u017Een\u00E9 distribuce rozv\u011Btven\u00FDch prepolymer\u016F nesouc\u00EDch reaktivn\u00ED skupiny. Hyperv\u011Btven\u00E9 polymery budou modifikov\u00E1ny zaveden\u00EDm incia\u010Dn\u00EDch jader a slo\u017Eek upravuj\u00EDc\u00EDch jejich flexibilitu a termomechanick\u00E9 chov\u00E1n\u00ED. Mechanochemick\u00E9ho z\u00FA\u017Een\u00ED distribuc\u00ED bude dosahov\u00E1no ultrazvukov\u00FDm gener\u00E1torem. Tvorba s\u00EDt\u00ED bude charakterizov\u00E1ny kineticky a zm\u011Bnami z\u00E1kladn\u00EDch strukturn\u00EDch parametr\u016F." . "http://www.isvav.cz/projectDetail.do?rowId=IAA4050808"^^ . . . . . . "15"^^ . "Teor. byly pops\u00E1ny a exper. ov\u011B\u0159eny zp\u016Fsoby regulace struktury hyperv\u011Btven\u00FDch polymer\u016F, funk\u010Dn\u00EDch hv\u011Bzd a funk\u010Dn\u00EDch kopolymer\u016F a jejich s\u00ED\u0165ov\u00E1n\u00ED polyisokyan\u00E1ty. Byly objasn\u011Bny jejich transformace a funkce v tenk\u00FDch ochran. filmech."@cs . "The aims are:to characterize precursors of polymer networks of compact architecture and reactivity of their functional groups; to elucidate crosslinking of precursors and to characterize the network structure and properties including potential applications. The precursors considered include hyperbranched polymers obtained from BAf monomers, reactive microgels obtained by emulsion polymerization and mechanochemically narrowed distributions of branched polymers carrying reactive goups. The hyperbranched polymers will be modified by introduction of %22seed%22 cores and components modifying their flexibility and thermal behaviour. An ultrasound generator will be used for mechanochemical narrowing of distributions. The precursors will be characterized by their molecular weight and functional group reactivity distributions. Network formation will be characterized by changes of the most important kinetic and structural parameters."@en . "15"^^ . "Kompaktn\u00ED nanometrov\u00E9 prekursory polymern\u00EDch s\u00EDt\u00ED:s\u00ED\u0165ov\u00E1n\u00ED a struktura s\u00EDt\u00ED" . "Compact Nanosized Precursors of Polymer Networks: Crosslinking and Network Properties"@en . . . . "IAA4050808" . "0"^^ . . . . "1"^^ . . . .