. "Charge transfer in organized supramolecular assemblies of fullerenes"@en . . . "This is a proposal to investigate electrochemical charge-transfer in fullerenes C60 C70 and endohedral fullerenes either in the form of organized films on supports or in supramolecular complexes inside carbon nanotubes (%22fullerene peapods%22). The project includes also own synthesis and characterization (Vis-NIR, Raman, SEM, XRD, SPM, ESCA) of the mentioned materials from commerical fullerenes and nanotubes. Besides usual electrochemical techniques, electrochemical impedance and quartz microbalance will be employed. Charge-transfer reactions will serve for tuning and monitoring of electronic structure with the aim of spectroelectrochemical methods (Vis-NIR, Raman) for structural characterization and analysis. In peapods, fundamental questions about the interaction of fullerene with the nanotube-double-layer will be addressed. The charge transfer reactions will be utilized for self-organization of fullerene layers and for templating of metal clusters. Morphological analysis will be carried out by SPM."@en . "P\u0159enos n\u00E1boje v organizovan\u00FDch supramolekul\u00E1rn\u00EDch soustav\u00E1ch fulleren\u016F" . "0"^^ . " Organized nanostructures" . . "35"^^ . . . "35"^^ . . "1"^^ . . . "The results confirmed the significance of charge transfer, both electrochemical and via redox active molecules or atoms, towards extending our knowledge on organized fullerene assemblies and other related nanocarbon materials"@en . . . " Fullerene peapods" . "http://www.isvav.cz/projectDetail.do?rowId=IAA4040306"^^ . . "Podstatou n\u00E1vrhu je elektrochemick\u00FD v\u00FDzkum reakce p\u0159enosu n\u00E1boje u fulleren\u016F C60, C70 a endohedr\u00E1ln\u00EDch fulleren\u016F ve form\u011B organizovan\u00FDch film\u016F na podlo\u017Ece a supramolekul\u00E1rn\u00EDho komplexu fullerenu v uhl\u00EDkov\u00E9 nanotuby. Sou\u010D\u00E1st\u00ED projektu je i vlastn\u00ED preparace a charakterizace (Vis-NIR, Raman, SEM, XRD, SPM, ESCA) t\u011Bchto l\u00E1tek z komer\u010Dn\u011B dostupn\u00FDch materi\u00E1l\u016F. Krom\u011B b\u011B\u017En\u00FDch elektrochemick\u00FDch metod bude pou\u017Eito elektrochemick\u00E9 impedance a k\u0159emenn\u00FDch mikrov\u00E1h. Reakce p\u0159enosu n\u00E1boje budou vyu\u017Eity k nastaven\u00ED a monitorov\u00E1n\u00ED zm\u011Bn elektronov\u00E9 struktury pro vypracov\u00E1n\u00ED spektroelektrochemick\u00E9 metody (Vis-NIR, Raman) pro strukturn\u00ED charakterizaci a anal\u00FDzu t\u011Bchto l\u00E1tek. U %22peapods%22 budou poprv\u00E9 prostudov\u00E1ny z\u00E1kladn\u00ED ot\u00E1zky interakce fulleren\u016F s el. dvojvrstvou nanotuby p\u0159i elektrochemick\u00E9m dopov\u00E1n\u00ED. P\u0159enos n\u00E1boje bude vyu\u017Eit k samoorganizaci vrstev fulleren\u016F do fullerenov\u00FDch klastr\u016F pro templ\u00E1tov\u00E1n\u00ED kovov\u00FDch klastr\u016F. Pro mofrologickou anal\u00FDzu bude vyu\u017Eito SPM, v\u010D. m\u011B\u0159en\u00ED in-situ v elektrolytech." . "Fulleren; Fullerene peapods; Organized nanostructures; Charge transfer"@en . . "0"^^ . "2009-04-03+02:00"^^ . . . "IAA4040306" . "V\u00FDsledky dokazuj\u00ED v\u00FDznam p\u0159enosu n\u00E1boje, a\u0165 u\u017E prov\u00E1d\u011Bn\u00E9ho elektrochemicky nebo pomoc\u00ED redox aktivn\u00EDch molekul \u010Di atom\u016F pro roz\u0161\u00ED\u0159en\u00ED na\u0161ich znalost\u00ED o organizovan\u00FDch soustav\u00E1ch fulleren\u016F a souvisej\u00EDc\u00EDch nanouhl\u00EDkat\u00FDch materi\u00E1lech"@cs . . . . "Fulleren" . . .