"macrocyclization" . . . "Fullerenov\u00E9 kontejnery. N\u00E1vrh, synt\u00E9za, vlastnosti a mo\u017En\u00E9 aplikace." . "IAA400550704" . "A large series of electron-rich thiamacrocycles as well as oligodentate ligands bearing TTF-arms was synthesized, all aimed at fullerene complexation. Preliminary experiments confirmed the interaction of selected ligands with the fullerene C60."@en . . "Fullerene Containers. Design, Synthesis, Properties and Possible Application."@en . . . "2007-01-01+01:00"^^ . . . . "2011-12-31+01:00"^^ . "macrocyclization; template; fullerenes; inclusion complexes"@en . "0"^^ . "1"^^ . "2013-06-28+02:00"^^ . "2011-03-18+01:00"^^ . "Projekt p\u0159edkl\u00E1d\u00E1 \u0159adu aromatick\u00FDch velkoobjemov\u00FDch analog cyklodextrin\u016F navr\u017Eenou pro ulo\u017Een\u00ED fullerenu formou 1:1 inklusn\u00EDch komplex\u016F. Navr\u017Een\u00E1 architektura vyu\u017E\u00EDv\u00E1 atraktivn\u00EDch interakc\u00ED mezi aromatick\u00FDm hostitelsk\u00FDm interi\u00E9rem a fullerenem k podpo\u0159e tvorby inklusn\u00EDho komplexu, zat\u00EDmco perifern\u00ED funkcionalizace optimalizuje jeho rozpustnost v \u0161irok\u00E9m spektru rozpou\u0161t\u011Bdel v\u010Detn\u011B vody. Je navr\u017Eeno vyu\u017Eit\u00ED p\u0159i konstrukci molekul\u00E1rn\u00EDch reaktor\u016F ur\u010Den\u00FDch pro regioselektivn\u00ED modifikaci fulleren\u016F. N\u011Bkter\u00E9 navr\u017Een\u00E9 reaktory jsou chir\u00E1ln\u00ED a umo\u017E\u0148uj\u00ED tak sou\u010Dasn\u011B i enantioselektivn\u00ED rozli\u0161en\u00ED. D\u00E1le je navr\u017Eena origin\u00E1ln\u00ED chemick\u00E9 transformace ur\u010Den\u00E1 specificky pro cyklotetramern\u00ED anthracenov\u00E9 inklusn\u00ED komplexy s fullerenem, jej\u00EDm\u017E c\u00EDlem je tvorba vysoce uspo\u0159\u00E1dan\u00FDch kovalentn\u00EDch 1D a 2D fullerenov\u00FDch struktur vyu\u017Eiteln\u00FDch v molekul\u00E1rn\u00ED elektronice a p\u0159i konstrukci chemick\u00FDch sensor\u016F." . "0"^^ . . . "Project provides series of large-diameter aromatic analogues of cyclodextrins allowing to accommodate fullerenes via 1: 1 host-guest inclusion complexes. The proposed architecture exploits attractive interaction between aromatic interior of the designed hosts and fullerene surface in promotion of the complexes. Periphery of the hosts is designed to mitigate solubility problems and to allow operation in a broad variety of solvents, including water. Novel application is proposed in the design of molecular reactors aimed at regioselective modification of fullerene molecules. Chirality of some of the proposed hosts allows also enantiodiscrimination in the transformation process. Novel chemical transformation is proposed specifically for the cyclotetrameric anthracene \u2013 fullerene complexes, which is directed to formation of highly ordered covalent 1D and 2D fullerene architectures, applicable in molecular electronics and in the design of chemical sensors."@en . . " fullerenes" . . . . " template" . . . "5"^^ . "5"^^ . . "http://www.isvav.cz/projectDetail.do?rowId=IAA400550704"^^ . "Byl syntetizov\u00E1n rozs\u00E1hl\u00FD soubor elektronov\u011B bohat\u00FDch thiamakrocykl\u016F a necyklick\u00FDch ligand\u016F obsahuj\u00EDc\u00EDch ramena s TTF skupinami, ur\u010Den\u00FDch pro komplexaci fulleren\u016F. P\u0159edb\u011B\u017En\u00E1 m\u011B\u0159en\u00ED potvrdila u vybran\u00FDch ligand\u016F interakci s fullerenem C60."@cs . .