" intensities" . " of" . " spectral" . . . " transition" . . "fine; and; hyperfine; interaction; transition; probabilities; ALMA; intensities; and; profiles; of; spectral; peaks; free; radicals"@en . . . "fine" . . "The main result of the project is correct theoretical analysis of stationary states of FCO2 and FSO3 radicals. The results, adequately described in the closing summary, are important for interpretation of high-resolution spectra. The output are three original papers published in impacted journals. Failure to comply with the rules of the grant or disbursement of funds were not identified."@en . . " peaks" . . . . "2014-01-27+01:00"^^ . " free" . . "V\u00FDpo\u010Det a anal\u00FDza vysoce rozli\u0161en\u00FDch mikrovlnn\u00FDch spekter atmosf\u00E9ricky a astrofyzik\u00E1ln\u011B zaj\u00EDmav\u00FDch molekul" . "2009-01-01+01:00"^^ . "6"^^ . " and" . "6"^^ . . "2012-03-30+02:00"^^ . "0"^^ . " probabilities" . "GP203/09/P306" . . "1"^^ . . . . "Projekt je zam\u011B\u0159en na fyzik\u00E1ln\u011B p\u0159esnou anal\u00FDzu vysoce rozli\u0161en\u00FDch mikrovlnn\u00FDch spekter mal\u00FDch molekul, iont\u016F i radik\u00E1l\u016F, kter\u00E9 se nach\u00E1z\u00ED v atmosf\u00E9\u0159e a v mezihv\u011Bzdn\u00E9m prost\u0159ed\u00ED. Zahrnuje v\u00FDpo\u010Det jemn\u00FDch a hyperjemn\u00FDch st\u011Bp\u00EDc\u00EDch konstant, intenzit slab\u00FDch elektrick\u00FDch kvadrup\u00F3lov\u00FDch a magnetick\u00FDch dip\u00F3lov\u00FDch (tzv. zak\u00E1zan\u00FDch) p\u0159echod\u016F a modelov\u00E1n\u00ED profil\u016F spektr\u00E1ln\u00EDch \u010Dar. K teoretick\u00FDm v\u00FDpo\u010Dt\u016Fm elektronov\u00FDch struktur, rota\u010Dn\u011B-vibra\u010Dn\u00EDch hladin a hyperjemn\u00FDch \u0161t\u011Bp\u00EDc\u00EDch konstant bude pou\u017Eito kvalitn\u00EDch p\u0159esn\u00FDch ab initio metod (CCSD(T) a MRCI). Projekt poskytne zejm\u00E9na d\u016Fle\u017Eit\u00E9 spektroskopick\u00E9 \u00FAdaje pro kvalitativn\u00ED anal\u00FDzu dat z mikrovlnn\u00FDch teleskop\u016F (ALMA) a kvantitativn\u00ED anal\u00FDzu atmosf\u00E9rick\u00FDch spekter reaktivn\u00EDch radik\u00E1l\u016F. V\u00FDsledky zefektivn\u00ED vyu\u017Eit\u00ED unik\u00E1tn\u00EDho spektrometru v Laborato\u0159i vysoce rozli\u0161en\u00E9 molekulov\u00E9 spektroskopie v Praze." . . " ALMA" . "2012-12-31+01:00"^^ . " hyperfine" . . "0"^^ . "http://www.isvav.cz/projectDetail.do?rowId=GP203/09/P306"^^ . . "Hlavn\u00EDm v\u00FDsledkem projektu je korektn\u00ED teoretick\u00E1 anal\u00FDza stacion\u00E1rn\u00EDch stav\u016F radik\u00E1l\u016F FCO2 a FSO3. V\u00FDsledky, adekv\u00E1tn\u011B popsan\u00E9 v z\u00E1v\u011Bre\u010Dn\u00E9 kart\u011B, maj\u00ED v\u00FDznam pro interpretaci spekter vysok\u00E9ho rozli\u0161en\u00ED. V\u00FDstupem jsou publikovan\u00E9 t\u0159i p\u016Fvodn\u00ED \u010Dl\u00E1nky v impaktovan\u00FDch \u010Dasopisech. Nedostatky v dodr\u017Eov\u00E1n\u00ED grantov\u00FDch pravidel nebo v \u010Derp\u00E1n\u00ED finan\u010Dn\u00EDch prost\u0159edk\u016F nebyly zji\u0161t\u011Bn\u00E9."@cs . "The project is focused on physically correct analyses of high resolved microwave spectra of small molecules, ions and radicals, which occur in the Earth's atmosphere and in the interstellar medium. It includes calculations of fine and hyperfine splitting constants, intensities of weak electric quadrupole and magnetic dipole (forbidden) transitions, and modelling of spectral line shapes. The high accurate ab initio methods (CCSD(T) and MRCI) will be used for calculating electronic structures, rotational-vibrational energy levels, and fine and hyperfine splitting constants. The project yields in particular, important spectroscopic knowledge of the structure of small species for qualitative analyses of data from the microwave telescopes (ALMA) and qualitative analyses of atmospheric spectra of small reactive free radicals. The results contribute to the more effective usage of the unique spectrometer in the Laboratory of high resolution molecular spectroscopy in Prague."@en . " interaction" . "Calculations and analyses of high resolution microwave spectra of species of atmospheric and astrophysical interest"@en . " profiles" .