. " supramolecular chemistry" . "2007-01-01+01:00"^^ . "2015-01-22+01:00"^^ . . "2009-12-31+01:00"^^ . . . . . . "GP203/07/P382" . "0"^^ . . "cucurbituril" . "http://www.isvav.cz/projectDetail.do?rowId=GP203/07/P382"^^ . "0"^^ . . . "1"^^ . "cucurbituril; supramolecular chemistry; molecular recognition"@en . . . "."@en . . "Nov\u00E9 deriv\u00E1ty cucurbit[n]urilu" . "Tento projekt se bude zab\u00FDvat p\u0159\u00EDpravou nov\u00FDch deriv\u00E1t\u016F cucurbit[n]uril\u016F. Budou studov\u00E1ny faktory ovliv\u0148uj\u00EDc\u00ED velikost a slo\u017Een\u00ED makrocyklu zahrnuj\u00EDc\u00ED volbu a pom\u011Br v\u00FDchoz\u00EDch l\u00E1tek, druh rozpou\u0161t\u011Bdla a reak\u010Dn\u00ED teplotu. Bude zvolena vhodn\u00E1 separa\u010Dn\u00ED metoda vedouc\u00ED k z\u00EDsk\u00E1n\u00ED po\u017Eadovan\u00E9ho deriv\u00E1tu cucurbit[n]urilu. Budou stanoveny konstanty stability komplex\u016F deriv\u00E1t\u016F cucurbit[n]uril\u016F se zvolen\u00FDmi hostitelsk\u00FDmi molekulami. Na jejich z\u00E1klad\u011B bude ur\u010Den vliv modifikace makrocyklu na jeho komplexa\u010Dn\u00ED vlastnosti. Reakc\u00ED mezi polymery (oligomery) a vybran\u00FDmi deriv\u00E1ty cucurbit[n]uril\u016F budou p\u0159ipraveny supramolekul\u00E1rn\u00ED polyvalentn\u00ED syst\u00E9my." . "20"^^ . . . . "20"^^ . . "New cucurbit[n]uril derivatives"@en . . . "Projekt byl \u0159e\u0161en zodpov\u011Bdn\u011B a m\u00E1 adekv\u00E1tn\u00ED v\u00FDstupy patentov\u00E9 i publika\u010Dn\u00ED. Autor projektu a jeho spolupracovn\u00EDci vyvinuli dva r\u016Fzn\u00E9 zp\u016Fsoby synt\u00E9zy nov\u00FDch modifikovan\u00FDch cucurbituril\u016F. Prvn\u00ED zp\u016Fsob spo\u010D\u00EDval v reakc\u00EDch mezi glykolurilem a r\u016Fzn\u00FDmi aldehydy"@cs . "2009-04-22+02:00"^^ . . "This project will investigate the preparation of new cucurbit[n]uril derivatives. Different factor which influence the composition and size of the macrocycles will be studied including choice and ratio of starting materials, type of solvent and reaction temperature. Suitable separation technique will be found to obtain desired cucurbit[n]uril derivative. In order to determine the influence of macrocycle modification on its binding properties the stability constants of complexes between cucurbit[n]uril derivatives and different guest molecules will be measured. The supramolecular polyvalent systems will be prepared using reactions between selected cucurbit[n]uril derivatives and polymers or oligomers."@en .