"2009-04-22+02:00"^^ . . "2015-01-22+01:00"^^ . . . . . " liquid flow analytical techniques" . . "amperometric detection; liquid flow analytical techniques; boron doped diamond; amalgam electrodes"@en . . "."@en . . "C\u00EDlem navrhovan\u00E9ho projektu\u00A0je konstrukce\u00A0a charakteristika elektrochemick\u00FDch detektor\u016F kompatibiln\u00EDch s analytick\u00FDmi\u00A0pr\u016Ftokov\u00FDmi syst\u00E9my a jejich\u00A0vyu\u017Eit\u00ED\u00A0pro stanoven\u00ED biologicky aktivn\u00EDch organick\u00FDch l\u00E1tek. P\u0159i konstrukci detektor\u016F budou pou\u017Eity netradi\u010Dn\u00ED elektrodov\u00E9 materi\u00E1ly a\u00A0sledov\u00E1ny z\u00E1kladn\u00ED\u00A0opera\u010Dn\u00ED parametry detektor\u016F (nap\u0159. citlivost, limit detekce, line\u00E1rn\u00ED dynamick\u00FD rozsah atd.) i jejich dynamick\u00E9 charakteristiky. Odezva detektor\u016F bude sledov\u00E1na i v z\u00E1vislosti na vz\u00E1jemn\u00E9m uspo\u0159\u00E1d\u00E1n\u00EDelektrod v m\u011B\u0159\u00EDc\u00ED cele. Netradi\u010Dn\u00ED elektrodov\u00E9 materi\u00E1ly, konkr\u00E9tn\u011B nano- a mikrokrystalick\u00FD diamant dopovan\u00FD b\u00F3rem\u00A0bude testov\u00E1n p\u0159i\u00A0tenkovrstv\u00E9m uspo\u0159\u00E1d\u00E1n\u00ED m\u011B\u0159\u00EDc\u00ED cely. Pevn\u00E9 amalg\u00E1mov\u00E9 elektrody um\u00EDst\u011Bn\u00E9 v p\u0159epadov\u00FDch n\u00E1dobk\u00E1ch budou pou\u017Eity ve wall jet uspo\u0159\u00E1d\u00E1n\u00ED. D\u016Fraz\u00A0bude kladen na\u00A0pou\u017Eitelnost detek\u010Dn\u00EDch cel ve spojen\u00ED s FIA, SIA a HPLC. Navr\u017Een\u00E9 detektory\u00A0budou n\u00E1sledn\u011B pou\u017Eity p\u0159i v\u00FDvoji nov\u00FDch\u00A0metod pro stanoven\u00ED nanomol\u00E1rn\u00EDch koncentrac\u00ED amino, hydroxy a nitro deriv\u00E1t\u016F polycyklick\u00FDch" . "amperometric detection" . "C\u00EDle projektu se poda\u0159ilo zcela splnit. Byly zkonstruov\u00E1ny a porovn\u00E1v\u00E1ny t\u0159i typy amp\u00E9romatrick\u00FDch cel pro m\u011B\u0159en\u00ED v pr\u016Fto\u010Dn\u00FDch syst\u00E9mech. Vyvinut\u00E9 detek\u010Dn\u00ED syst\u00E9my byly aplikov\u00E1ny p\u0159i stanoven\u00ED polutant\u016F \u017Eivotn\u00EDho prost\u0159ed\u00ED, pesticid\u016F a l\u00E9\u010Div, obsahuj\u00EDc\u00EDc"@cs . "0"^^ . . "1"^^ . . . " boron doped diamond" . "The proposed project is devoted to the\u00A0construction, characterization and use of electrochemical detectors\u00A0compatible with\u00A0liquid flow analytical techniques and applicable on the determination of biologically active organic compounds. New\u00A0detectors will be constructed using novel electrode materials and electrode arrangments in electrochemical cells and their principal analytical parameters (i.e. sensitivity, limit of detection, linear dynamic range etc.) and dynamic characteristics\u00A0will be investigated. Non-traditional electrode materials,\u00A0namely, nano- and microcrystalline boron doped diamond will be used in a thin-layer electrochemical cell. Solid amalgam electrodes will be employed for amperometric detection in wall jet arrangment in overflow cells. The scope and limitations for the use of these materials in\u00A0FIA, SIA and HPLC will be\u00A0tested. Consequently, new methods will be developed for the determination of nanomolar concentrations of\u00A0amino, hydroxy, and nitro derivatives of"@en . . "0"^^ . . . . "2007-01-01+01:00"^^ . . "GP203/07/P261" . "http://www.isvav.cz/projectDetail.do?rowId=GP203/07/P261"^^ . . . "27"^^ . "27"^^ . "Nov\u00E9 mo\u017Enosti elektrochemick\u00E9 detekce biologicky aktivn\u00EDch organick\u00FDch l\u00E1tek v pr\u016Ftokov\u00FDch metod\u00E1ch" . "New possibilities of electrochemical detection of biologically active organic compounds in liquid flow analytical methods"@en . "2009-12-31+01:00"^^ .