"0"^^ . . "1"^^ . "2008-05-19+02:00"^^ . . . . . . . . . . "Organometallic Compounds of Divalent Metals of 14th Group"@en . "Neuvedeno."@en . . "http://www.isvav.cz/projectDetail.do?rowId=GP203/02/D169"^^ . "During the years 2002 - 2005, ca 75 of new organometallic or coocrdination compounds have been prepared . The main classes of these compounds were organotin(IV), organotin(II), organolead(II) etc. All these compounds were characterized in solution and so"@en . "Podstatou projektu je v\u00FDzkum struktury a vlastnost\u00ED organokovov\u00FDch slou\u010Denin p\u0159edev\u0161\u00EDm divalentn\u00EDch kov\u016F 14-t\u00E9 skupiny v\u00A0r\u016Fzn\u00FDch typech roztok\u016F a tuh\u00E9 f\u00E1zi pomoc\u00ED NMR, CP/MAS NMR a rentgenov\u00FDch difrak\u010Dn\u00EDch technik. Tyto slou\u010Deniny jsou velice m\u00E1loprostudov\u00E1ny hlavn\u011B kv\u016Fli jejich nestabilit\u011B, kter\u00E1 je v\u00A0navrhovan\u00FDch slou\u010Denin\u00E1ch \u010D\u00E1ste\u010Dn\u011B odstran\u011Bna pou\u017Eit\u00EDm C, Y-chel\u00E1tuj\u00EDch ligand\u016F." . . . "Organokovov\u00E9 slou\u010Deniny dvojmocn\u00FDch kov\u016F 14-t\u00E9 skupiny" . "15"^^ . "The aim of the research will be structure and behaviour study of organometallic compounds with 14th group metals in different types of solutions and in the solid state using NMR, CP/MAS NMR and X-ray diffraction techniques. Above mentioned compounds arerarely studies mainly due to their low thermal stability. This type of unstability in compounds proposed by us partially eliminated by involving of C, Y-chelating ligands."@en . "GP203/02/D169" . . "15"^^ . . "B\u011Bhem let 2002 - 2005 bylo p\u0159ipraveno cca. 75 nov\u00FDch, literatu\u0159e dosud nepopsan\u00FDch, organokovov\u00FDch slou\u010Denin, a to hlavn\u011B organoc\u00EDni\u010Dit\u00FDch, organoc\u00EDnat\u00FDch, organoolovnat\u00FDch aj. U v\u0161ech t\u011Bchto slou\u010Denin byla provedena charakterizace jak v tuh\u00E9 f\u00E1zi tak i"@cs . . . . "0"^^ . .