"Metallocene (Ti, Zr, or Hf) derivatives bearing auxiliary highly substituted cyclopentadienyl ligands will be investigated for their ability to react with bonding electrons in the auxiliary ligands as well as in simple molecules and unsaturated hydrocarbons upon thermal, photolytical, or reduction-induced metal activation. New metallocene-derived skeletons will be synthesized, and a number of C-C bond forming reactions will be effected with new catalytically active complexes."@en . "Metaloceny 4 skupiny: aktivace ligand\u016F pro syntetick\u00E9 a katalytick\u00E9 aplikace" . . "2012-01-01+01:00"^^ . "http://www.isvav.cz/projectDetail.do?rowId=GAP207/12/2368"^^ . . "Bude studov\u00E1na schopnost metalocenov\u00FDch (Ti, Zr nebo Hf) deriv\u00E1t\u016F nesouc\u00EDch pomocn\u00E9 vysoce substituovan\u00E9 cyklopentadienylov\u00E9 ligandy reagovat s vazebn\u00FDmi elektrony na t\u011Bchto ligandech, jako\u017E i s jednoduch\u00FDmi molekulami a nenasycen\u00FDmi uhlovod\u00EDky v d\u016Fsledku teplotn\u00ED, fotolytick\u00E9 nebo redukc\u00ED indukovan\u00E9 aktivace kovov\u00E9ho atomu. S takto p\u0159ipraven\u00FDmi strukturn\u011B nov\u00FDmi slou\u010Deninami odvozen\u00FDmi od klasick\u00FDch metalocen\u016F, bude provedena \u0159ada reakc\u00ED p\u0159i nich\u017E doch\u00E1z\u00ED k vzniku vazby C-C, v kter\u00FDch tyto komplexy budou slou\u017Eit jako katalyticky aktivn\u00ED \u010D\u00E1stice." . "2014-03-31+02:00"^^ . "metallocene ligand activation substitution of ligands catalysis photolysis thermolysis"@en . . . . . . "8"^^ . . "8"^^ . "2015-04-23+02:00"^^ . "Group 4 metallocenes: activation of ligands for synthetic and catalytic applications"@en . . "1"^^ . . "GAP207/12/2368" . . "2016-12-31+01:00"^^ . . "0"^^ . . . "0"^^ . . . . . .