"2014-12-31+01:00"^^ . . . . "Development of new methodologies towards (pentafluorosulfanyl)benzenes."@en . "C\u00EDl projektu, v\u00FDvoj nov\u00FDch metodik derivatizace (pentafluorsulfanyl)benzen\u016F, byl spln\u011Bn. Substituce nitroskupiny, oxidativn\u00ED a z\u00E1stupn\u00E1 substituce aromatick\u00E9ho vod\u00EDku, borylace a jodace diazoniov\u00FDch sol\u00ED nebo oxidace arom\u00E1t\u016F umo\u017E\u0148uj\u00ED p\u0159\u00EDpravu nov\u00FDch slou\u010Denin s SF5 skupinu pro dal\u0161\u00ED syntetick\u00E9 vyu\u017Eit\u00ED. V\u00FDsledky projektu byly publikov\u00E1ny formou 6 publikac\u00ED v mezin\u00E1rodn\u00EDch impaktovan\u00FDch \u010Dasopisech."@cs . "SF5 pentafluorosulfanyl nucleophilic aromatic substitution nitrobenzene"@en . . "7"^^ . . . "7"^^ . "The aim of the project, development of derivatization of (pentafluorosulfanyl)benzenes, was achieved. Substitution of nitro group, aromatic oxidative and vicarious substitution, borylation and iodination through aryldiazonium salts or oxidation of aromatics enabled the preparation of compounds bearing SF5 group. The results of the project were published in 6 highly impacted international journals."@en . . "GAP207/12/0072" . . "0"^^ . . "1"^^ . . . . "2012-01-01+01:00"^^ . "2014-03-31+02:00"^^ . "http://www.isvav.cz/projectDetail.do?rowId=GAP207/12/0072"^^ . . "0"^^ . "We propose to investigate the following reactions of nitro-(pentafluorosulfanyl)benzenes: (a) nucleophilic aromatic substitution for the nitro group, (b) oxidative nucleophilic aromatic substitution for the hydrogen and (c) vicarious nucleophilic substitution for hydrogen. This approach will significantly improve the access to various chemically diverse and selectively functionalized SF5-benzenes and accelerate the development of applications of this highly promising but still relatively rare class of compounds."@en . "Navrhujeme prozkoumat n\u00E1sleduj\u00EDc\u00ED reakce nitro-(pentafluorsulfanyl)benzen\u016F: (a) nukleofiln\u00ED aromatickou substituci za nitro skupinu, (b) oxidativn\u00ED nukleofiln\u00ED aromatickou substituci za vod\u00EDk a (c) z\u00E1stupnou nukleofiln\u00ED substituci za vod\u00EDk. Tento p\u0159\u00EDstup povede k mnohem lep\u0161\u00ED dostupnosti rozmanit\u00FDch selektivn\u011B substituovan\u00FDch SF5-benzen\u016F a urychl\u00ED rozvoj aplikac\u00ED tohoto velmi perspektivn\u00EDho, ale st\u00E1le je\u0161t\u011B relativn\u011B vz\u00E1cn\u00E9ho typu slou\u010Denin." . . . . . "2015-05-22+02:00"^^ . "V\u00FDvoj nov\u00FDch metodologi\u00ED pro p\u0159\u00EDpravu (pentafluorsulfanyl)benzen\u016F." . .