. "GA203/95/0105" . "Local Conformations in Peptide Molecules Probed by Raman Optical Activity:Experiment and Theory"@en . . . . . "Ramanovsk\u00E1 optick\u00E1 aktivita jako lok\u00E1ln\u00ED konforma\u010Dn\u00ED sonda v molekul\u00E1ch peptid\u016F: experiment a teorie" . "13"^^ . "http://www.isvav.cz/projectDetail.do?rowId=GA203/95/0105"^^ . "13"^^ . . . . . . "0"^^ . . "Navrhujeme zjistit, zda data z\u00EDskan\u00E1 pomoc\u00ED Ramansk\u00E9 optick\u00E9 aktivity jsou citliv\u00E1 ke zm\u011Bn\u00E1m prostorov\u00E9ho uspo\u0159\u00E1d\u00E1n\u00ED peptid\u016F. R\u00E1di bychom studovali vibra\u010Dn\u00ED mody o ni\u017E\u0161\u00EDch energi\u00EDch pro l\u00E1tky ve vodn\u00E9m roztoku. Chceme nal\u00E9zt, zda Ramansk\u00E1 optick\u00E1 aktivita m\u016F\u017Ee p\u0159isp\u011Bt k objas\u0148ov\u00E1n\u00ED konformace krat\u0161\u00EDch degment\u016F polypeptidov\u00E9ho \u0159et\u011Bzce, uspo\u0159\u00E1d\u00E1n\u00ED jeho obr\u00E1tek, ke konformaci disulfidov\u00FDch m\u016Fstk\u016F a k ot\u00E1zce potenci\u00E1ln\u00ED neplanarity amidov\u00FDch skupin. Pro tento \u00FA\u010Del m\u00E1me v \u00FAmyslu a) p\u0159ipravit vhodn\u00E9 modelov\u00E9 l\u00E1tky, b) sestavit experiment\u00E1ln\u00ED za\u0159\u00EDzen\u00ED, c) implementovat teoretick\u00FD v\u00FDpo\u010Det ROA dat (zalo\u017Een\u00FD na ab initio) a d) prov\u00E9st detailn\u00ED srovn\u00E1n\u00ED v\u00FDpo\u010Det-experiment." . . "1"^^ . "1"^^ . . .