"0"^^ . . . . . "XXX"@cs . . "1"^^ . . "http://www.isvav.cz/projectDetail.do?rowId=GA203/93/0246"^^ . "1"^^ . . . "Struktura a reaktivita iont\u016F v plynn\u00E9 f\u00E1zi" . . "GA203/93/0246" . "Structure and Reactivity of Gas Phase Ions"@en . . . . "10"^^ . "10"^^ . "Tento spole\u010Dn\u00FD projekt akademick\u00E9 a universitn\u00ED instituce je n\u00E1vrhem na v\u00FDzkum biomolekulov\u00FDch a mononukleov\u00FDch reakc\u00ED iont\u016F v plynn\u00E9 f\u00E1zi. Dynamika chemick\u00FDch reakc\u00ED iont\u016F s molekulami bude sledov\u00E1na metodou rozptylu ve zk\u0159\u00ED\u017Een\u00FDch paprsc\u00EDch \u010D\u00E1stic s c\u00EDlem objasnit sr\u00E1\u017Ekov\u00FD mechanismus, energetiku a (p\u0159em\u011Bny energie v element\u00E1rn\u00EDch chemick\u00FDch procesech vybran\u00FDch typ\u016F (rozpad meziproduktu - komplexu, p\u0159enos hydroidov\u00E9ho iontu, reakce negativn\u00EDch iont\u016F, p\u0159enos n\u00E1boje s \u00FA\u010Dast\u00ED n\u00E1sobn\u011B nabit\u00FDch iont\u016F). Moomolekulov\u00E9 rozpady polyatomov\u00FDch organick\u00FDch molekul budou sledov\u00E1ny po ionizaci elektrony vysok\u00FDch energi\u00ED (0.1 - 2 keV) s c\u00EDlem nal\u00E9zt podm\u00EDnky ionizace, p\u0159i nich\u017E struktur\u00E1ln\u011B v\u00FDznamn\u011B p\u0159\u00EDm\u00E9 disociace p\u0159eva\u017Euj\u00EDc\u00ED nad procesy p\u0159esmyku iont\u016F. Tento novp\u0159\u00EDstup je d\u016Fle\u017Eit\u00FD z hlediska objas\u0148ov\u00E1n\u00ED struktury molekul pomoc\u00ED metod hmotnostn\u00ED spektrometrie." . .