"Tvorba vazeb za uvoln\u011Bn\u00ED vod\u00EDku katalyzovan\u00E1 komplexy titanu" . "0"^^ . "katal\u00FDza" . " polysilany" . "Dehydrocoupling reactions catalyzed by titanium complexes"@en . "2015-03-02+01:00"^^ . . . . . "C\u00EDlem projektu je prozkoum\u00E1n\u00ED katalytick\u00FDch schopnost\u00ED syst\u00E9m\u016F tvo\u0159en\u00FDch titani\u010Dit\u00FDm komplexem a alkyla\u010Dn\u00EDm \u010Dinidlem p\u0159i tvorb\u011B vazeb mezi prvky hlavn\u00ED skupiny za uvoln\u011Bn\u00ED vod\u00EDku (katalytick\u00E9m dehydrocouplingu)." . "2011-04-16+02:00"^^ . . . . "The project gone according to plan both in terms of expertise and in terms of disbursement of funds."@en . . . "The present project deals with the reactivity of titanium catalytic systems toward hydrogen-main group element bond (H-E) mainly in silanes (primary, secondary). The catalytic reaction will lead to formation of E-E bond or bonds (formation of dimers, oligomers or polymers) with concomitant releasing H2.Titanium catalytic systems will be generated by treatment of titanium(IV) complexes with different molar ratio of alkylating species. The predominant interest will be focused on the role of stabilizing ligands and oxidation state of the active titanium center on the reactivity of proposed catalytic systems and properties of prepared polymers. The effect of chiral ligand (BINOLs) stabilizing titanium center on the stereoregularity of produced polymers will be evaluated."@en . " dehydrokapling" . . "2011-12-31+01:00"^^ . . . "5"^^ . . . . . "5"^^ . "katal\u00FDza, dehydrokapling, polysilany, komplexy titanu"@en . . "2009-01-01+01:00"^^ . "\u0158e\u0161en\u00ED projektu prob\u011Bhlo podle pl\u00E1nu jak z hlediska odborn\u00E9ho tak i z hlediska \u010Derp\u00E1n\u00ED finan\u010Dn\u00EDch prost\u0159edk\u016F."@cs . . "1"^^ . "GA203/09/1574" . . . "2"^^ . "http://www.isvav.cz/projectDetail.do?rowId=GA203/09/1574"^^ .