. . "http://www.isvav.cz/projectDetail.do?rowId=GA203/00/0600"^^ . . . . "38"^^ . . . . "38"^^ . . "Description of thermodynamics properties of fluids at superambient conditions by the methods of applied statistical mechanics"@en . "Neuvedeno."@en . . "1"^^ . "C\u00EDlem navr\u017Een\u00E9ho projektu je podstatn\u00E9 zlep\u0161en\u00ED popisu rovnov\u00E1\u017En\u00E9ho stavov\u00E9ho a f\u00E1zov\u00E9ho chov\u00E1n\u00ED jedno- i v\u00EDceslo\u017Ekov\u00FDch tekut\u00FDch soustav poz\u016Fst\u00E1vaj\u00EDc\u00EDch z nesf\u00E9rick\u00FDch (a p\u0159\u00EDpadn\u011B i pol\u00E1rn\u00EDch) molekul. Termodynamick\u00E9 rovnov\u00E1hy budou studov\u00E1ny experiment\u00E1ln\u00EDmi metodami (stanoven\u00EDm dodatkov\u00FDch objem\u016F a Gibbsov\u00FDch funkc\u00ED sm\u011Bs\u00ED), molekul\u00E1rn\u00EDmi po\u010D\u00EDta\u010Dov\u00FDmi simulacemi modelov\u00FDch syst\u00E9m\u016F a s pou\u017Eit\u00EDm poruchov\u00E9 teorie kapalin. Jako v\u00FDchoz\u00ED modelov\u00E1 tekutina bude slou\u017Eit soustava nesf\u00E9rick\u00FDch konvexn\u00EDch molekul interaguj\u00EDc\u00EDch prost\u0159ednictv\u00EDm generalizovan\u00E9ho kiharovsk\u00E9ho mezimolekul\u00E1rn\u00EDho potenci\u00E1lu. V\u00FDzkum bude soust\u0159ed\u011Bn na chov\u00E1n\u00ED \u010Dist\u00FDch l\u00E1tek v okol\u00ED kritick\u00E9ho bodu kapalina - p\u00E1ra a na chov\u00E1n\u00ED bin\u00E1rn\u00EDch a v\u00EDceslo\u017Ekov\u00FDch sm\u011Bs\u00ED jak za norm\u00E1ln\u00EDch podm\u00EDnek tak i veli\u010Diny budou detailn\u011B studov\u00E1ny t\u0159et\u00ED a vy\u0161\u0161\u00ED viri\u00E1ln\u00ED koeficienty soustav tvo\u0159en\u00FDch nesf\u00E9rick\u00FDmi molekulami, a to jak s pou\u017Eit\u00EDm numerick\u00FDch tak i teoretick\u00FDch metod; v t\u00E9to souvislosti se chceme pokusit tak\u00E9 o zdokonalen\u00ED" . "1"^^ . . "2008-05-19+02:00"^^ . "The aim of the proposed project is to substantially improve the description of the equilibrium state and phase behaviour of multicomponent fluid systems composed of non-spherical (and polar) molecules. Thermodynamic equilibrium will be studied both by experimental methods (including determinations of excess volumes and Gibbs functions of mixtures), molecular simulations of model systems on computers, and by applying the perturbation theory of liquids. The system of non-spherical particles interacting via the Kihara intermolecular potential will serve as the primary underlying model fluid. The research will focus on the behaviour of pure systems in the vicinity of the vapour-liquid critical point and on the behaviour of binary and multicomponent mixtures at normal conditions and at elevated pressures and/or temperatures. In order to develop valid equation of state and expressions for related thermodynamic functions we will study also the third and higher virial coefficients of non-spherical"@en . . . "GA203/00/0600" . "0"^^ . . "Po celou dobu dotov\u00E1n\u00ED projektu byl konstatov\u00E1n vysok\u00FD odborn\u00FD p\u0159\u00EDnos \u0159e\u0161itele i spolu\u0159e\u0161itele. Sv\u011Bd\u010D\u00ED o tom vysoce nadstandartn\u00ED po\u010Det publikac\u00ED v presti\u017En\u00EDch mezin\u00E1rodn\u00EDch \u010Dasopisech (!). Jsme p\u0159esv\u011Bd\u010Deni, \u017Ee pr\u00E1ce na projektu zahrnovala i v\u00FDchovu mlad"@cs . . "Popis termodynamick\u00E9ho chov\u00E1n\u00ED tekutin za superambientn\u00EDch podm\u00EDnek metodami aplikovan\u00E9 statistick\u00E9 mechaniky" . . . .