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Statements

Subject Item
n2:RIV%2F70883521%3A28610%2F13%3A43870121%21RIV14-GA0-28610___
rdf:type
skos:Concept n17:Vysledek
dcterms:description
The chemiluminescence of UV irradiated aromatic-aliphatic polyesters Ecoflex was examined in nitrogen and oxygen atmosphere during non-isothermal temperature runs in the interval from 40° to 250°C. With prolongation of UV irradiation period, the character of hydroperoxides in the Ecoflex changed, and the less stable hydroperoxides predominated. The half times of hydroperoxide decomposition, estimated from chemiluminescence measurements at 58°C, were comparable with the mineralization times of the above polymers in composting biodegradation experiments, which may indicate the supporting role of UV light to the final conversion of polyesters to carbon dioxide in their biodegradation. The chemiluminescence of UV irradiated aromatic-aliphatic polyesters Ecoflex was examined in nitrogen and oxygen atmosphere during non-isothermal temperature runs in the interval from 40° to 250°C. With prolongation of UV irradiation period, the character of hydroperoxides in the Ecoflex changed, and the less stable hydroperoxides predominated. The half times of hydroperoxide decomposition, estimated from chemiluminescence measurements at 58°C, were comparable with the mineralization times of the above polymers in composting biodegradation experiments, which may indicate the supporting role of UV light to the final conversion of polyesters to carbon dioxide in their biodegradation.
dcterms:title
Chemiluminescence from pre-oxidized ecoflex polymers Chemiluminescence from pre-oxidized ecoflex polymers
skos:prefLabel
Chemiluminescence from pre-oxidized ecoflex polymers Chemiluminescence from pre-oxidized ecoflex polymers
skos:notation
RIV/70883521:28610/13:43870121!RIV14-GA0-28610___
n17:predkladatel
n18:orjk%3A28610
n3:aktivita
n19:S n19:P
n3:aktivity
P(ED2.1.00/03.0111), P(GAP108/10/0200), S
n3:dodaniDat
n10:2014
n3:domaciTvurceVysledku
n13:3917436 n13:8588716
n3:druhVysledku
n14:C
n3:duvernostUdaju
n6:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
65243
n3:idVysledku
RIV/70883521:28610/13:43870121
n3:jazykVysledku
n16:eng
n3:klicovaSlova
Chemiluminescence, aromatic-aliphatic polyesters Ecoflex, biodegradation, hydroperoxides, UV irradiation
n3:klicoveSlovo
n4:UV%20irradiation n4:hydroperoxides n4:Chemiluminescence n4:biodegradation n4:aromatic-aliphatic%20polyesters%20Ecoflex
n3:kontrolniKodProRIV
[BB9F0A67CDE7]
n3:mistoVydani
Germany
n3:nazevEdiceCisloSvazku
Neuveden
n3:nazevZdroje
Natural and artificial ageing of polymers
n3:obor
n15:CD
n3:pocetDomacichTvurcuVysledku
2
n3:pocetStranKnihy
349
n3:pocetTvurcuVysledku
6
n3:projekt
n12:ED2.1.00%2F03.0111 n12:GAP108%2F10%2F0200
n3:rokUplatneniVysledku
n10:2013
n3:tvurceVysledku
Rychlý, Josef Rychlá, Lyda Commereuc, Sophie Verney, Vincent Koutný, Marek Stloukal, Petr
s:numberOfPages
10
n21:hasPublisher
Gesellschaft fur Umweltsimulation e.V. GUS
n7:isbn
978-3-9813136-8-0
n5:organizacniJednotka
28610