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Statements

Subject Item
n2:RIV%2F70883521%3A28140%2F14%3A43871536%21RIV15-MSM-28140___
rdf:type
n14:Vysledek skos:Concept
rdfs:seeAlso
http://www.electrochemsci.org/papers/vol9/91206910.pdf
dcterms:description
In this study, potential sweep technique and controlled potential electrolysis were used to analyze the electrochemical oxidation of glycerin in a three electrode system using platinum as a working electrode. Electrochemical experiments were performed at different concentrations of glycerin and manganese dioxide (0.015-0.124 M) to analyze the reaction order of reactant and oxidant.Voltammograms were studied at different positive and negative potential limits (-1.5 to 1.5 V vs Ag/AgCl), sweep rates (0.01 to 0.08 V/s) and temperatures (27 to 60 °C). The influence of each parameter on the voltammogram shape is discussed. Prolonged electrolysis at controlled potential yield glyceraldehyde, glyceric acid and glycolid acid as the main products. In this study, potential sweep technique and controlled potential electrolysis were used to analyze the electrochemical oxidation of glycerin in a three electrode system using platinum as a working electrode. Electrochemical experiments were performed at different concentrations of glycerin and manganese dioxide (0.015-0.124 M) to analyze the reaction order of reactant and oxidant.Voltammograms were studied at different positive and negative potential limits (-1.5 to 1.5 V vs Ag/AgCl), sweep rates (0.01 to 0.08 V/s) and temperatures (27 to 60 °C). The influence of each parameter on the voltammogram shape is discussed. Prolonged electrolysis at controlled potential yield glyceraldehyde, glyceric acid and glycolid acid as the main products.
dcterms:title
Electrooxidation of Glycerin by Potential Sweep Technique and Controlled Potential Electrolysis Electrooxidation of Glycerin by Potential Sweep Technique and Controlled Potential Electrolysis
skos:prefLabel
Electrooxidation of Glycerin by Potential Sweep Technique and Controlled Potential Electrolysis Electrooxidation of Glycerin by Potential Sweep Technique and Controlled Potential Electrolysis
skos:notation
RIV/70883521:28140/14:43871536!RIV15-MSM-28140___
n3:aktivita
n4:P
n3:aktivity
P(ED2.1.00/03.0089)
n3:cisloPeriodika
9
n3:dodaniDat
n7:2015
n3:domaciTvurceVysledku
n15:6724388 n15:8963967
n3:druhVysledku
n19:J
n3:duvernostUdaju
n11:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
14226
n3:idVysledku
RIV/70883521:28140/14:43871536
n3:jazykVysledku
n16:eng
n3:klicovaSlova
glycerin, potential sweep, controlled potential, anodic oxidation, platinum electrode
n3:klicoveSlovo
n9:platinum%20electrode n9:controlled%20potential n9:potential%20sweep n9:glycerin n9:anodic%20oxidation
n3:kodStatuVydavatele
RS - Srbská republika
n3:kontrolniKodProRIV
[1DFA4EF85338]
n3:nazevZdroje
International Journal of Electrochemical Sciences
n3:obor
n13:CG
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
3
n3:projekt
n5:ED2.1.00%2F03.0089
n3:rokUplatneniVysledku
n7:2014
n3:svazekPeriodika
2014
n3:tvurceVysledku
Kolomazník, Karel Beltrán Prieto, Juan Carlos Slavík, Roman
n3:wos
000345261900019
s:issn
1452-3981
s:numberOfPages
14
n17:organizacniJednotka
28140