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Statements

Subject Item
n2:RIV%2F70883521%3A28110%2F11%3A43865618%21RIV12-MSM-28110___
rdf:type
n9:Vysledek skos:Concept
dcterms:description
The dependence of the intrinsic viscosity [η] on the weight average degree of polymerization Pw of chitosans in aqueous acid media is discussed in terms of the Yamakawa-Fujii theory for the worm-like cylinder model. The conformational characteristics (Kuhn statistical segment length and Flory characteristic ratio) are estimated. They increase linearly with th reciprocal of the square root of salt concentration. The %22intrinsic%22 values for uncharged chains are comparable to those for cellulose and lower man those for chitin. The dependence of the intrinsic viscosity [η] on the weight average degree of polymerization Pw of chitosans in aqueous acid media is discussed in terms of the Yamakawa-Fujii theory for the worm-like cylinder model. The conformational characteristics (Kuhn statistical segment length and Flory characteristic ratio) are estimated. They increase linearly with th reciprocal of the square root of salt concentration. The %22intrinsic%22 values for uncharged chains are comparable to those for cellulose and lower man those for chitin.
dcterms:title
Intrinsic viscosity and conformational parameters of chitosan chains Intrinsic viscosity and conformational parameters of chitosan chains
skos:prefLabel
Intrinsic viscosity and conformational parameters of chitosan chains Intrinsic viscosity and conformational parameters of chitosan chains
skos:notation
RIV/70883521:28110/11:43865618!RIV12-MSM-28110___
n9:predkladatel
n15:orjk%3A28110
n3:aktivita
n4:V
n3:aktivity
V
n3:cisloPeriodika
2
n3:dodaniDat
n16:2012
n3:domaciTvurceVysledku
n7:6067808 n7:6247229 n7:2414309
n3:druhVysledku
n11:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n6:predkladatel
n3:idSjednocenehoVysledku
205582
n3:idVysledku
RIV/70883521:28110/11:43865618
n3:jazykVysledku
n10:eng
n3:klicovaSlova
Worm-like cylinder model; Intrinsic viscosity; Conformational parameters; Chitosan
n3:klicoveSlovo
n5:Chitosan n5:Worm-like%20cylinder%20model n5:Intrinsic%20viscosity n5:Conformational%20parameters
n3:kodStatuVydavatele
IN - Indická republika
n3:kontrolniKodProRIV
[18DAF1680927]
n3:nazevZdroje
Rasayan Journal of Chemistry: an international quarterly research journal of chemical sciences
n3:obor
n18:CF
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n16:2011
n3:svazekPeriodika
4
n3:tvurceVysledku
Šimek, Lubomír Halabalová, Věra Mokrejš, Pavel
s:issn
0974-1496
s:numberOfPages
19
n14:organizacniJednotka
28110