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Statements

Subject Item
n2:RIV%2F70883521%3A28110%2F03%3A63501411%21RIV%2F2004%2FMSM%2F281104%2FN
rdf:type
skos:Concept n14:Vysledek
dcterms:description
Under mild reaction conditions, the thiocyanato group is selectively transferred from 1-methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione (3) to some nucleophiles. Aliphatic primary and secondary amines are converted to S-cyanothiohydroxylamines, anilines afford p-thiocyanatoanilines, Wittig reagent is thiocyanated in ?-position, and thiols are oxidized to disulfides. Under mild reaction conditions, the thiocyanato group is selectively transferred from 1-methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione (3) to some nucleophiles. Aliphatic primary and secondary amines are converted to S-cyanothiohydroxylamines, anilines afford p-thiocyanatoanilines, Wittig reagent is thiocyanated in ?-position, and thiols are oxidized to disulfides.
dcterms:title
1-Methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione: A Novel Thiocyanating Agent 1-Methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione: A Novel Thiocyanating Agent
skos:prefLabel
1-Methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione: A Novel Thiocyanating Agent 1-Methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione: A Novel Thiocyanating Agent
skos:notation
RIV/70883521:28110/03:63501411!RIV/2004/MSM/281104/N
n5:strany
747-752
n5:aktivita
n18:Z
n5:aktivity
Z(MSM 265200015)
n5:cisloPeriodika
40
n5:dodaniDat
n7:2004
n5:domaciTvurceVysledku
n13:8577552 n13:1748734
n5:druhVysledku
n12:J
n5:duvernostUdaju
n9:S
n5:entitaPredkladatele
n11:predkladatel
n5:idSjednocenehoVysledku
636716
n5:idVysledku
RIV/70883521:28110/03:63501411
n5:jazykVysledku
n15:eng
n5:klicovaSlova
thiocyanates, thiocyanation, amines, thiols
n5:klicoveSlovo
n6:thiocyanation n6:thiocyanates n6:amines n6:thiols
n5:kodStatuVydavatele
US - Spojené státy americké
n5:kontrolniKodProRIV
[C686C8C7353C]
n5:nazevZdroje
Journal of Heterocyclic Chemistry
n5:obor
n16:CC
n5:pocetDomacichTvurcuVysledku
2
n5:pocetTvurcuVysledku
2
n5:pocetUcastnikuAkce
0
n5:pocetZahranicnichUcastnikuAkce
0
n5:rokUplatneniVysledku
n7:2003
n5:svazekPeriodika
Neuveden
n5:tvurceVysledku
Klásek, Antonín Mrkvička, Vladimír
n5:zamer
n17:MSM%20265200015
s:issn
0022-152X
s:numberOfPages
6
n4:organizacniJednotka
28110