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Statements

Subject Item
n2:RIV%2F70883521%3A28110%2F03%3A63501159%21RIV%2F2004%2FGA0%2F281104%2FN
rdf:type
skos:Concept n19:Vysledek
dcterms:description
Molecular modeling revealed the interlayer structure and differences in intercalation behaviour of Cetylpyridinium (CP) and Cetyltrimethylammonium (CTA) cations montmorillonite. CTA-montmorillonite exhibits significantly higher total sublimation energy and higher host-guest interaction energy than the CP-montmorillonite. The main difference between both intercalates is in charge distribution on the host layers and guest species, The charge transfer from the guest species to the host layer is higher in CTA-montmorillonite, than in CP-montmorillonites, and consequently the charge polarisation between the host and guest layers is much higher in CTA-montmorillonite. This leads to much stronger host-guest electrostatic interaction in case of CTA-montmorillonite. Results are established as a basic data for polymer/clay nanocomposite systems. Molecular modeling revealed the interlayer structure and differences in intercalation behaviour of Cetylpyridinium (CP) and Cetyltrimethylammonium (CTA) cations montmorillonite. CTA-montmorillonite exhibits significantly higher total sublimation energy and higher host-guest interaction energy than the CP-montmorillonite. The main difference between both intercalates is in charge distribution on the host layers and guest species, The charge transfer from the guest species to the host layer is higher in CTA-montmorillonite, than in CP-montmorillonites, and consequently the charge polarisation between the host and guest layers is much higher in CTA-montmorillonite. This leads to much stronger host-guest electrostatic interaction in case of CTA-montmorillonite. Results are established as a basic data for polymer/clay nanocomposite systems.
dcterms:title
Intercalated Clays - Precursors for Polymer-Clay Nanocomposites Intercalated Clays - Precursors for Polymer-Clay Nanocomposites
skos:prefLabel
Intercalated Clays - Precursors for Polymer-Clay Nanocomposites Intercalated Clays - Precursors for Polymer-Clay Nanocomposites
skos:notation
RIV/70883521:28110/03:63501159!RIV/2004/GA0/281104/N
n3:strany
CD
n3:aktivita
n17:Z n17:P
n3:aktivity
P(GA106/02/0205), Z(MSM 265200015)
n3:dodaniDat
n6:2004
n3:domaciTvurceVysledku
n14:9161287 n14:2849739
n3:druhVysledku
n8:D
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
610868
n3:idVysledku
RIV/70883521:28110/03:63501159
n3:jazykVysledku
n7:eng
n3:klicovaSlova
Polymer Nanocomposites, Clay, Intercalated Structure
n3:klicoveSlovo
n15:Intercalated%20Structure n15:Clay n15:Polymer%20Nanocomposites
n3:kontrolniKodProRIV
[759411C489E3]
n3:mistoKonaniAkce
Melbourne, Astrálie
n3:mistoVydani
Melbourne, Austrálie
n3:nazevZdroje
PPS-19 Melbourne
n3:obor
n20:CD
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
5
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n12:GA106%2F02%2F0205
n3:rokUplatneniVysledku
n6:2003
n3:tvurceVysledku
Weiss, Zdeněk Čapková, Pavla Pospíšil, Miroslav Šimoník, Josef Kovářová, Lucie
n3:typAkce
n21:WRD
n3:zahajeniAkce
2003-07-07+02:00
n3:zamer
n16:MSM%20265200015
s:numberOfPages
4
n4:hasPublisher
Polymer Processing Society
n11:organizacniJednotka
28110