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Statements

Subject Item
n2:RIV%2F68407700%3A21340%2F12%3A00205009%21RIV14-MSM-21340___
rdf:type
skos:Concept n12:Vysledek
dcterms:description
N-(4,6-dichloro-1,3,5-triazin-2-yl)-2-aminoanthracene was synthesized by substitution of one chlorine atom of 2,4,6-trichloro-1,3,5-triazine with 2-aminoanthracene. A new series of N-triazinyl-2-aminoanthracenes was prepared by nucleophilic substitution of one or both chlorine atoms on N-(4,6-dichloro-1,3,5-triazin-2-yl)-2-aminoanthracene with electron-donating methoxy or phenylamino groups. The UV/Vis absorption, fluorescence and excitation spectra as well as the fluorescence quantum yields of the prepared compounds were measured in 1,4-dioxane, ethyl acetate, dibutyl ether and acetonitrile; nanosecond kinetics of the fluorescence decay was measured in different solvents. The influence of the character of the substituent on triazinyl ring and of the solvent polarity upon the absorption and fluorescence spectra and fluorescence quantum yields are discussed. N-(4,6-dichloro-1,3,5-triazin-2-yl)-2-aminoanthracene was synthesized by substitution of one chlorine atom of 2,4,6-trichloro-1,3,5-triazine with 2-aminoanthracene. A new series of N-triazinyl-2-aminoanthracenes was prepared by nucleophilic substitution of one or both chlorine atoms on N-(4,6-dichloro-1,3,5-triazin-2-yl)-2-aminoanthracene with electron-donating methoxy or phenylamino groups. The UV/Vis absorption, fluorescence and excitation spectra as well as the fluorescence quantum yields of the prepared compounds were measured in 1,4-dioxane, ethyl acetate, dibutyl ether and acetonitrile; nanosecond kinetics of the fluorescence decay was measured in different solvents. The influence of the character of the substituent on triazinyl ring and of the solvent polarity upon the absorption and fluorescence spectra and fluorescence quantum yields are discussed.
dcterms:title
Synthesis, absorption and fluorescence properties of N-triazinyl derivatives of 2-aminoanthracene Synthesis, absorption and fluorescence properties of N-triazinyl derivatives of 2-aminoanthracene
skos:prefLabel
Synthesis, absorption and fluorescence properties of N-triazinyl derivatives of 2-aminoanthracene Synthesis, absorption and fluorescence properties of N-triazinyl derivatives of 2-aminoanthracene
skos:notation
RIV/68407700:21340/12:00205009!RIV14-MSM-21340___
n12:predkladatel
n17:orjk%3A21340
n3:aktivita
n9:S n9:I n9:Z
n3:aktivity
I, S, Z(MSM0021627501)
n3:cisloPeriodika
3
n3:dodaniDat
n16:2014
n3:domaciTvurceVysledku
n11:1299832 n11:5952069
n3:druhVysledku
n6:J
n3:duvernostUdaju
n20:S
n3:entitaPredkladatele
n13:predkladatel
n3:idSjednocenehoVysledku
172907
n3:idVysledku
RIV/68407700:21340/12:00205009
n3:jazykVysledku
n14:eng
n3:klicovaSlova
2-aminoanthracene; Synthesis; N-derivatives; UV/Vis spectra; Fluorescence quantum yield; Fluorescence quenching
n3:klicoveSlovo
n4:Fluorescence%20quenching n4:Fluorescence%20quantum%20yield n4:2-aminoanthracene n4:N-derivatives n4:Synthesis n4:UV%2FVis%20spectra
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[7FA24F04856F]
n3:nazevZdroje
Dyes and Pigments
n3:obor
n15:CC
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
8
n3:rokUplatneniVysledku
n16:2012
n3:svazekPeriodika
92
n3:tvurceVysledku
Bureš, F. Michl, Martin Čermák, J. El-Sedik, M. Dvořák, Miroslav Hrdina, R. Almonasy, N. Nepraš, Miloš
n3:wos
000298024300034
n3:zamer
n5:MSM0021627501
s:issn
0143-7208
s:numberOfPages
6
n19:doi
10.1016/j.dyepig.2011.08.018
n7:organizacniJednotka
21340