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Statements

Subject Item
n2:RIV%2F68407700%3A21340%2F09%3A00163371%21RIV10-GA0-21340___
rdf:type
skos:Concept n16:Vysledek
dcterms:description
Radiation and chemical stabilities of CMPO-functionalised calix[4]arenes, promising ligands for extraction of actinides and lanthanides, were studied both in Solution and in the solid state. A comparison of the results showed that the degradation of ligands under radiolytic conditions proceeds indirectly via interactions with the solvent. The radiation stabilities in chloroform and I-octanol were systematically studied using model compounds, and the main degradation product under extraction conditions (organic phase/conc. HNO3) was characterised. Radiation and chemical stabilities of CMPO-functionalised calix[4]arenes, promising ligands for extraction of actinides and lanthanides, were studied both in Solution and in the solid state. A comparison of the results showed that the degradation of ligands under radiolytic conditions proceeds indirectly via interactions with the solvent. The radiation stabilities in chloroform and I-octanol were systematically studied using model compounds, and the main degradation product under extraction conditions (organic phase/conc. HNO3) was characterised.
dcterms:title
Radiation and chemical stability of calix[4]arene derivatives as prospective liquid-liquid extractants Radiation and chemical stability of calix[4]arene derivatives as prospective liquid-liquid extractants
skos:prefLabel
Radiation and chemical stability of calix[4]arene derivatives as prospective liquid-liquid extractants Radiation and chemical stability of calix[4]arene derivatives as prospective liquid-liquid extractants
skos:notation
RIV/68407700:21340/09:00163371!RIV10-GA0-21340___
n3:aktivita
n9:P
n3:aktivity
P(GA104/07/1242)
n3:cisloPeriodika
8
n3:dodaniDat
n4:2010
n3:domaciTvurceVysledku
n7:7347073 n7:5928028
n3:druhVysledku
n13:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
337960
n3:idVysledku
RIV/68407700:21340/09:00163371
n3:jazykVysledku
n6:eng
n3:klicovaSlova
Extraction; Calixarene; Synthesis; Radiation; Stability; CMPO
n3:klicoveSlovo
n8:Stability n8:Radiation n8:Extraction n8:Synthesis n8:CMPO n8:Calixarene
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[0C85CC4AE794]
n3:nazevZdroje
Radiochimica Acta
n3:obor
n18:CH
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
6
n3:projekt
n14:GA104%2F07%2F1242
n3:rokUplatneniVysledku
n4:2009
n3:svazekPeriodika
97
n3:tvurceVysledku
Čuba, Václav John, Jan
n3:wos
000269725500006
s:issn
0033-8230
s:numberOfPages
7
n10:organizacniJednotka
21340