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Statements

Subject Item
n2:RIV%2F68407700%3A21340%2F04%3A04104251%21RIV%2F2005%2FMSM%2F213405%2FN
rdf:type
skos:Concept n13:Vysledek
dcterms:description
Bylo testováno použití tří metod k analýze komplexace europia (2.310-7 - 510-4 M, značeného 152Eu) s huminovou kyselinou typu Aldrich (2-60 mg/L) při pH 4-6, iontové síle 0.01 nebo 0.1M (NaClO4) a stáří roztoku 1 a 7 d. Stupeň zakomplexování Eu zjištěný těmi metodami byl srovnán. Jedna ze tří modifikací dialýzy a ionexová metoda daly podobné výsledky. Výsledky ultrafiltrace byly odlišné a nesprávné v důsledku nedokonalé separace komplexníxh a iontových forem europia. Application of the three methods was tested for analysis of complexation in the system europium (2.310-7 - 510-4 M, labelled with 152Eu) and Aldrich humic acid (2-60 mg/L), pH 4-6, ionic strength 0.01 or 0.1(NaClO4), solution age 1 and 7 d. Extents of Eu complexation obtained by the methods were compared. One of three dialysis arrangements tested and ion exchange method gave similar results. Results of ultrafiltration were different and incorrect due to imperfect separation of complexed and ionic Eu forms. Application of the three methods was tested for analysis of complexation in the system europium (2.310-7 - 510-4 M, labelled with 152Eu) and Aldrich humic acid (2-60 mg/L), pH 4-6, ionic strength 0.01 or 0.1(NaClO4), solution age 1 and 7 d. Extents of Eu complexation obtained by the methods were compared. One of three dialysis arrangements tested and ion exchange method gave similar results. Results of ultrafiltration were different and incorrect due to imperfect separation of complexed and ionic Eu forms.
dcterms:title
Critical Assessment of Dialysis, Ion Exchange and Ultrafiltration as Methods for Analysis of Metal-Humate Complexation Kritické zhodnocení dialýzy, iontové výměny a ultrafiltrace jako metod analýzy komplexace kovů s humáty Critical Assessment of Dialysis, Ion Exchange and Ultrafiltration as Methods for Analysis of Metal-Humate Complexation
skos:prefLabel
Kritické zhodnocení dialýzy, iontové výměny a ultrafiltrace jako metod analýzy komplexace kovů s humáty Critical Assessment of Dialysis, Ion Exchange and Ultrafiltration as Methods for Analysis of Metal-Humate Complexation Critical Assessment of Dialysis, Ion Exchange and Ultrafiltration as Methods for Analysis of Metal-Humate Complexation
skos:notation
RIV/68407700:21340/04:04104251!RIV/2005/MSM/213405/N
n3:aktivita
n4:Z
n3:aktivity
Z(MSM 210000019)
n3:dodaniDat
n7:2005
n3:domaciTvurceVysledku
n9:8425582 n9:2603209 n9:1676512
n3:druhVysledku
n18:A
n3:duvernostUdaju
n11:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
558996
n3:idVysledku
RIV/68407700:21340/04:04104251
n3:jazykVysledku
n17:eng
n3:klicovaSlova
Europium; complexation; dialysis; humic acid; ion exchange; speciation; ultrafiltration
n3:klicoveSlovo
n6:humic%20acid n6:complexation n6:Europium n6:dialysis n6:ultrafiltration n6:speciation n6:ion%20exchange
n3:kodPristupu
n10:L
n3:kontrolniKodProRIV
[F771C9CB8AA8]
n3:mistoVydani
Praha
n3:nosic
neuvedeno
n3:obor
n14:CB
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n7:2004
n3:tvurceVysledku
Beneš, Petr Procházková, Šárka Štamberg, Karel
n3:zamer
n15:MSM%20210000019
n19:isbn
80-01-02945-X
n12:organizacniJednotka
21340