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Statements

Subject Item
n2:RIV%2F68378271%3A_____%2F14%3A00436876%21RIV15-GA0-68378271
rdf:type
skos:Concept n18:Vysledek
dcterms:description
Whereas designing new chiral self-assembling materials i.e. those possessing the liquid crystalline behaviour, special attention should be paid to the specific architecture of different molecular parts, in particular molecular core, linkage groups, type and place of the lateral substituents, structure of the chiral centre and the chiral and non-chiral chains. For the first time a new chiral photosensitive liquid crystalline compound possessing an unconventional pentaglyform terminal unit attached to the non-chiral chain has been designed and synthesised. On cooling from the isotropic phase the material possesses two tilted phases: an ordinary smectic C* phase and smectic I* phase with hexagonal ordering. The self-assembling and structural behaviour have been studied by different techniques and compared to that of the materials with similar molecular structure but possessing structurally different terminal units in the non-chiral chain. Whereas designing new chiral self-assembling materials i.e. those possessing the liquid crystalline behaviour, special attention should be paid to the specific architecture of different molecular parts, in particular molecular core, linkage groups, type and place of the lateral substituents, structure of the chiral centre and the chiral and non-chiral chains. For the first time a new chiral photosensitive liquid crystalline compound possessing an unconventional pentaglyform terminal unit attached to the non-chiral chain has been designed and synthesised. On cooling from the isotropic phase the material possesses two tilted phases: an ordinary smectic C* phase and smectic I* phase with hexagonal ordering. The self-assembling and structural behaviour have been studied by different techniques and compared to that of the materials with similar molecular structure but possessing structurally different terminal units in the non-chiral chain.
dcterms:title
New chiral liquid crystal with unconventional dioxane terminal unit New chiral liquid crystal with unconventional dioxane terminal unit
skos:prefLabel
New chiral liquid crystal with unconventional dioxane terminal unit New chiral liquid crystal with unconventional dioxane terminal unit
skos:notation
RIV/68378271:_____/14:00436876!RIV15-GA0-68378271
n3:aktivita
n12:P n12:I
n3:aktivity
I, P(7AMB13PL041), P(7AMB14PL035), P(GA13-14133S), P(LD14007)
n3:cisloPeriodika
10-11
n3:dodaniDat
n15:2015
n3:domaciTvurceVysledku
n5:6743617 n5:1542362 n5:1315226
n3:druhVysledku
n14:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n13:predkladatel
n3:idSjednocenehoVysledku
32349
n3:idVysledku
RIV/68378271:_____/14:00436876
n3:jazykVysledku
n17:eng
n3:klicovaSlova
chiral liquid crysta; pentaglyform unit; structural properties; smectic phase; hexagonal ordering; self-assembling
n3:klicoveSlovo
n4:pentaglyform%20unit n4:chiral%20liquid%20crysta n4:self-assembling n4:hexagonal%20ordering n4:structural%20properties n4:smectic%20phase
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[DE543FBF58C1]
n3:nazevZdroje
Phase Transitions
n3:obor
n16:JJ
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
7
n3:projekt
n7:7AMB13PL041 n7:GA13-14133S n7:LD14007 n7:7AMB14PL035
n3:rokUplatneniVysledku
n15:2014
n3:svazekPeriodika
87
n3:tvurceVysledku
Perkowski, P. Bubnov, Alexej Kašpar, Miroslav Hamplová, Věra Piecek, W. Mrukiewicz, M. Pociecha, D.
n3:wos
000345840100014
s:issn
0141-1594
s:numberOfPages
14
n10:doi
10.1080/01411594.2014.953515