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Statements

Subject Item
n2:RIV%2F68378271%3A_____%2F14%3A00434926%21RIV15-AV0-68378271
rdf:type
n17:Vysledek skos:Concept
dcterms:description
Two new complexes, [Ni(HL1)(N3)(μ1,1N3)]2 (1) [HL1: NC5H4CH3C=NNH (C=O) NH2] and [Ni(L2)N3] (2) [HL2: NC5H4HC=N NH(C=S)NH2], have been synthesized by reaction of Ni(OAC)2.4H2O and sodium azide with HL1 and HL2 and characterized by elemental analysis, FT-IR, and UV-vis spectral studies. Single-crystal X-ray diffraction reveals that 1 is dinuclear with nickel(II) in an octahedral environment of NNO donors of HL1, two nitrogens of azide bridges and one nitrogen of terminal azide; 2 is mononuclear containing nickel(II) in a distorted square-planar environment of NNS donors of HL2 and one terminal az ide. The structures of 1 and 2 have been optimized by density functional theory. Two new complexes, [Ni(HL1)(N3)(μ1,1N3)]2 (1) [HL1: NC5H4CH3C=NNH (C=O) NH2] and [Ni(L2)N3] (2) [HL2: NC5H4HC=N NH(C=S)NH2], have been synthesized by reaction of Ni(OAC)2.4H2O and sodium azide with HL1 and HL2 and characterized by elemental analysis, FT-IR, and UV-vis spectral studies. Single-crystal X-ray diffraction reveals that 1 is dinuclear with nickel(II) in an octahedral environment of NNO donors of HL1, two nitrogens of azide bridges and one nitrogen of terminal azide; 2 is mononuclear containing nickel(II) in a distorted square-planar environment of NNS donors of HL2 and one terminal az ide. The structures of 1 and 2 have been optimized by density functional theory.
dcterms:title
Synthesis, crystal structures, antimicrobial activities, and DFT calculations of two new azido nickel(II) complexes Synthesis, crystal structures, antimicrobial activities, and DFT calculations of two new azido nickel(II) complexes
skos:prefLabel
Synthesis, crystal structures, antimicrobial activities, and DFT calculations of two new azido nickel(II) complexes Synthesis, crystal structures, antimicrobial activities, and DFT calculations of two new azido nickel(II) complexes
skos:notation
RIV/68378271:_____/14:00434926!RIV15-AV0-68378271
n3:aktivita
n11:I
n3:aktivity
I
n3:cisloPeriodika
12
n3:dodaniDat
n13:2015
n3:domaciTvurceVysledku
n6:9519106 n6:5796350
n3:druhVysledku
n14:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n12:predkladatel
n3:idSjednocenehoVysledku
49016
n3:idVysledku
RIV/68378271:_____/14:00434926
n3:jazykVysledku
n16:eng
n3:klicovaSlova
uranium complex; isothiosemicarbazone; crystallography; spectra; thermal stability
n3:klicoveSlovo
n4:isothiosemicarbazone n4:spectra n4:thermal%20stability n4:uranium%20complex n4:crystallography
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[32725C0D21B7]
n3:nazevZdroje
Journal of Coordination Chemistry
n3:obor
n15:BM
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
7
n3:rokUplatneniVysledku
n13:2014
n3:svazekPeriodika
67
n3:tvurceVysledku
Dušek, Michal Mukherjee, R. Mahmoudi, F. Shaabani, B. Maestro, M. A. Pojarová, Michaela Khandar, A. A.
n3:wos
000340154000006
s:issn
0095-8972
s:numberOfPages
14
n8:doi
10.1080/00958972.2014.936859