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Statements

Subject Item
n2:RIV%2F68378271%3A_____%2F13%3A00420745%21RIV14-AV0-68378271
rdf:type
n10:Vysledek skos:Concept
dcterms:description
The generation of gaseous singlet oxygen by gas-liquid reaction of chlorine with alkaline solution of hydrogen peroxide in spray form was studied experimentally on the originally designed device with a fast separation of reacted liquid from gas. The singlet oxygen yield, residual chlorine, and water vapor content in gas were measured under different experimental conditions of the centrifugal spray singlet oxygen generator (CSSOG) using nitrogen as a dilution gas. A characteristic feature of the CSSOG is a high utilization of the chemicals and production of singlet oxygen at a very high total pressure even near the atmospheric pressure. This generator developed originally for driving a chemical oxygen-iodine laser (COIL) could be employed also as an efficient singlet oxygen source in material science, chemical synthesis, and others. The generation of gaseous singlet oxygen by gas-liquid reaction of chlorine with alkaline solution of hydrogen peroxide in spray form was studied experimentally on the originally designed device with a fast separation of reacted liquid from gas. The singlet oxygen yield, residual chlorine, and water vapor content in gas were measured under different experimental conditions of the centrifugal spray singlet oxygen generator (CSSOG) using nitrogen as a dilution gas. A characteristic feature of the CSSOG is a high utilization of the chemicals and production of singlet oxygen at a very high total pressure even near the atmospheric pressure. This generator developed originally for driving a chemical oxygen-iodine laser (COIL) could be employed also as an efficient singlet oxygen source in material science, chemical synthesis, and others.
dcterms:title
High-power generator of singlet oxygen High-power generator of singlet oxygen
skos:prefLabel
High-power generator of singlet oxygen High-power generator of singlet oxygen
skos:notation
RIV/68378271:_____/13:00420745!RIV14-AV0-68378271
n10:predkladatel
n14:ico%3A68378271
n3:aktivita
n16:Z
n3:aktivity
Z(AV0Z10100523)
n3:cisloPeriodika
10
n3:dodaniDat
n15:2014
n3:domaciTvurceVysledku
n8:2668157 n8:6577024 n8:5142318 n8:8159386
n3:druhVysledku
n19:J
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n7:predkladatel
n3:idSjednocenehoVysledku
77416
n3:idVysledku
RIV/68378271:_____/13:00420745
n3:jazykVysledku
n18:eng
n3:klicovaSlova
high-pressure singlet oxygen generator; spray generator; centrifugal separation
n3:klicoveSlovo
n5:centrifugal%20separation n5:spray%20generator n5:high-pressure%20singlet%20oxygen%20generator
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[AC5024174EBE]
n3:nazevZdroje
Chemical Engineering & Technology
n3:obor
n17:BH
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:rokUplatneniVysledku
n15:2013
n3:svazekPeriodika
36
n3:tvurceVysledku
Špalek, Otomar Jirásek, Vít Čenský, Miroslav Kodymová, Jarmila
n3:wos
000327883500016
n3:zamer
n4:AV0Z10100523
s:issn
0930-7516
s:numberOfPages
10
n6:doi
10.1002/ceat.201300196