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Statements

Subject Item
n2:RIV%2F68378271%3A_____%2F12%3A00384806%21RIV13-AV0-68378271
rdf:type
skos:Concept n17:Vysledek
dcterms:description
The centrosymmetric dinuclear cadmium title complex was obtained by the reaction of N,N0-bis(2-aminoethyl)ethane-1,2-diamine (trien) with Cd(NO3)2. 4H2O and sodium perchlorate in methanol. The CdII cation is coordinated by four N atoms of a non-bridging trien ligand and by two N atoms of a bridging trien ligand in a slightly distorted octahedral coordination geometry. The bridging ligand shares another two N atoms with a neighboring symmetry-equivalent CdII cation. The structure displays C-H...O and N-H...O hydrogen bonding. The perchlorate anion is disordered. The centrosymmetric dinuclear cadmium title complex was obtained by the reaction of N,N0-bis(2-aminoethyl)ethane-1,2-diamine (trien) with Cd(NO3)2. 4H2O and sodium perchlorate in methanol. The CdII cation is coordinated by four N atoms of a non-bridging trien ligand and by two N atoms of a bridging trien ligand in a slightly distorted octahedral coordination geometry. The bridging ligand shares another two N atoms with a neighboring symmetry-equivalent CdII cation. The structure displays C-H...O and N-H...O hydrogen bonding. The perchlorate anion is disordered.
dcterms:title
[μ-N,N´-Bis(2-aminoethyl)ethane-1,2-diamine-κ4N1,N1´:N2,N2´]bis{[N,N’-bis(2-aminoethyl)ethane-1,2-diamine-κ4N,N’,N’’,N’’’] cadmium}tetrakis(perchlorate) [μ-N,N´-Bis(2-aminoethyl)ethane-1,2-diamine-κ4N1,N1´:N2,N2´]bis{[N,N’-bis(2-aminoethyl)ethane-1,2-diamine-κ4N,N’,N’’,N’’’] cadmium}tetrakis(perchlorate)
skos:prefLabel
[μ-N,N´-Bis(2-aminoethyl)ethane-1,2-diamine-κ4N1,N1´:N2,N2´]bis{[N,N’-bis(2-aminoethyl)ethane-1,2-diamine-κ4N,N’,N’’,N’’’] cadmium}tetrakis(perchlorate) [μ-N,N´-Bis(2-aminoethyl)ethane-1,2-diamine-κ4N1,N1´:N2,N2´]bis{[N,N’-bis(2-aminoethyl)ethane-1,2-diamine-κ4N,N’,N’’,N’’’] cadmium}tetrakis(perchlorate)
skos:notation
RIV/68378271:_____/12:00384806!RIV13-AV0-68378271
n17:predkladatel
n18:ico%3A68378271
n3:aktivita
n15:Z
n3:aktivity
Z(AV0Z10100521)
n3:cisloPeriodika
Part 9
n3:dodaniDat
n11:2013
n3:domaciTvurceVysledku
n19:5642272 n19:5796350
n3:druhVysledku
n8:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
183164
n3:idVysledku
RIV/68378271:_____/12:00384806
n3:jazykVysledku
n4:eng
n3:klicovaSlova
x-ray structure; cadmium; perchlorate; disorder; weak interactions
n3:klicoveSlovo
n6:perchlorate n6:weak%20interactions n6:x-ray%20structure n6:disorder n6:cadmium
n3:kodStatuVydavatele
DK - Dánské království
n3:kontrolniKodProRIV
[7434C319FC54]
n3:nazevZdroje
Acta Crystallographica section E - Structure Reports Online
n3:obor
n7:BM
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
4
n3:rokUplatneniVysledku
n11:2012
n3:svazekPeriodika
68
n3:tvurceVysledku
Dušek, Michal Goudarziafshar, H. Eigner, Václav Abbasityula, Y.
n3:zamer
n14:AV0Z10100521
s:issn
1600-5368
s:numberOfPages
9
n5:doi
10.1107/S1600536812033880