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Statements

Subject Item
n2:RIV%2F68378271%3A_____%2F11%3A00369756%21RIV12-AV0-68378271
rdf:type
n13:Vysledek skos:Concept
dcterms:description
The crystal structure of natural zippeite,K1.85H+0.15[(UO2)4O2(SO4)2(OH)2](H2O)4, from Jáchymov, Czech Republic, has been determined by single-crystal X-ray diffraction. Zippeite is monoclinic, space group C2/m, with a 8.7802(6), b 13.9903(12), c 8.8630(6) Å, beta 104.524(7)°, V 1053.92(12) Å3. The structure consists of structural sheets of the zippeite uranyl anion topology and an interlayer, in which split K atoms and disordered O atoms (of the H2O groups) are located. The structure unit >[(UO2)4O2(SO4)2(OH)2]2– is novel for both natural and synthetic compounds, but generally consistent with the known zippeite-type structures. The crystal structure of natural zippeite,K1.85H+0.15[(UO2)4O2(SO4)2(OH)2](H2O)4, from Jáchymov, Czech Republic, has been determined by single-crystal X-ray diffraction. Zippeite is monoclinic, space group C2/m, with a 8.7802(6), b 13.9903(12), c 8.8630(6) Å, beta 104.524(7)°, V 1053.92(12) Å3. The structure consists of structural sheets of the zippeite uranyl anion topology and an interlayer, in which split K atoms and disordered O atoms (of the H2O groups) are located. The structure unit >[(UO2)4O2(SO4)2(OH)2]2– is novel for both natural and synthetic compounds, but generally consistent with the known zippeite-type structures.
dcterms:title
The crystal structure of natural zippeite, K1.85H+0.15[(UO2)4O2(SO4)2(OH)2](H2O)4, from Jáchymov, Czech Republic The crystal structure of natural zippeite, K1.85H+0.15[(UO2)4O2(SO4)2(OH)2](H2O)4, from Jáchymov, Czech Republic
skos:prefLabel
The crystal structure of natural zippeite, K1.85H+0.15[(UO2)4O2(SO4)2(OH)2](H2O)4, from Jáchymov, Czech Republic The crystal structure of natural zippeite, K1.85H+0.15[(UO2)4O2(SO4)2(OH)2](H2O)4, from Jáchymov, Czech Republic
skos:notation
RIV/68378271:_____/11:00369756!RIV12-AV0-68378271
n13:predkladatel
n16:ico%3A68378271
n4:aktivita
n14:I n14:P n14:Z
n4:aktivity
I, P(GAP204/11/0809), Z(AV0Z10100521), Z(MK00002327201), Z(MSM0021622412)
n4:cisloPeriodika
4
n4:dodaniDat
n17:2012
n4:domaciTvurceVysledku
n15:8772274 n15:5796350
n4:druhVysledku
n12:J
n4:duvernostUdaju
n18:S
n4:entitaPredkladatele
n8:predkladatel
n4:idSjednocenehoVysledku
192356
n4:idVysledku
RIV/68378271:_____/11:00369756
n4:jazykVysledku
n10:eng
n4:klicovaSlova
uranyl minerals; X-ray diffraction; crystal structure; Jana2006; bond-valence approach
n4:klicoveSlovo
n6:bond-valence%20approach n6:crystal%20structure n6:X-ray%20diffraction n6:Jana2006 n6:uranyl%20minerals
n4:kodStatuVydavatele
CA - Kanada
n4:kontrolniKodProRIV
[133D1E62703A]
n4:nazevZdroje
Canadian Mineralogist
n4:obor
n5:BM
n4:pocetDomacichTvurcuVysledku
2
n4:pocetTvurcuVysledku
8
n4:projekt
n20:GAP204%2F11%2F0809
n4:rokUplatneniVysledku
n17:2011
n4:svazekPeriodika
49
n4:tvurceVysledku
Fejfarová, Karla Škoda, R. Plášil, J. Dušek, Michal Čejka, J. Novák, M. Mills, S. J. Sejkora, J.
n4:wos
000296699100013
n4:zamer
n11:AV0Z10100521 n11:MK00002327201 n11:MSM0021622412
s:issn
0008-4476
s:numberOfPages
14
n19:doi
10.3749/canmin.49.4.1089