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Statements

Subject Item
n2:RIV%2F68378271%3A_____%2F10%3A00355611%21RIV11-MSM-68378271
rdf:type
skos:Concept n18:Vysledek
dcterms:description
In this work, the first direct measurement of inter and intra-layer molecular self-diffusion in the smectic phases of a chiral smectogen (S)-2-methylbutyl-[4-(4%22-heptyloxyphenyl)-benzoyl-4-oxy-(S)-2-((S) -2)-benzoyl)-propionyl)]-propionate (ZLL7/*) by means of pulsed field gradient NMR is reported. Self-diffusion coefficients as low as 10 -13 m2 s-1 have been measured by combining magic echo spin decoupling with a stimulated echo sequence. The transitions among synclinic-anticlinic smectic phases are associated with a change in the self-diffusion coefficients. In this work, the first direct measurement of inter and intra-layer molecular self-diffusion in the smectic phases of a chiral smectogen (S)-2-methylbutyl-[4-(4%22-heptyloxyphenyl)-benzoyl-4-oxy-(S)-2-((S) -2)-benzoyl)-propionyl)]-propionate (ZLL7/*) by means of pulsed field gradient NMR is reported. Self-diffusion coefficients as low as 10 -13 m2 s-1 have been measured by combining magic echo spin decoupling with a stimulated echo sequence. The transitions among synclinic-anticlinic smectic phases are associated with a change in the self-diffusion coefficients.
dcterms:title
Translational self-diffusion in the synclinic to anticlinic phases of a ferroelectric liquid crystal Translational self-diffusion in the synclinic to anticlinic phases of a ferroelectric liquid crystal
skos:prefLabel
Translational self-diffusion in the synclinic to anticlinic phases of a ferroelectric liquid crystal Translational self-diffusion in the synclinic to anticlinic phases of a ferroelectric liquid crystal
skos:notation
RIV/68378271:_____/10:00355611!RIV11-MSM-68378271
n4:aktivita
n12:P n12:Z
n4:aktivity
P(GA202/09/0047), P(IAA100100911), P(OC10006), Z(AV0Z10100520)
n4:cisloPeriodika
23
n4:dodaniDat
n13:2011
n4:domaciTvurceVysledku
n11:2213273
n4:druhVysledku
n15:J
n4:duvernostUdaju
n17:S
n4:entitaPredkladatele
n16:predkladatel
n4:idSjednocenehoVysledku
293351
n4:idVysledku
RIV/68378271:_____/10:00355611
n4:jazykVysledku
n9:eng
n4:klicovaSlova
chiral smectogen; echo sequences; ferroelectric liquid crystal; intra-layer; molecular self-diffusion; pulsed field gradient NMR
n4:klicoveSlovo
n5:pulsed%20field%20gradient%20NMR n5:echo%20sequences n5:chiral%20smectogen n5:intra-layer n5:ferroelectric%20liquid%20crystal n5:molecular%20self-diffusion
n4:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n4:kontrolniKodProRIV
[F14F6E208FB3]
n4:nazevZdroje
Soft Matter
n4:obor
n6:BM
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
5
n4:projekt
n8:GA202%2F09%2F0047 n8:IAA100100911 n8:OC10006
n4:rokUplatneniVysledku
n13:2010
n4:svazekPeriodika
6
n4:tvurceVysledku
Dvinskikh, S. V. Veracini, A. Glogarová, Milada Cifelli, M. Domenici, V.
n4:wos
000284313700022
n4:zamer
n14:AV0Z10100520
s:issn
1744-683X
s:numberOfPages
5