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Statements

Subject Item
n2:RIV%2F68378050%3A_____%2F12%3A00387886%21RIV13-GA0-68378050
rdf:type
n3:Vysledek skos:Concept
dcterms:description
Ferrocenestrone, the first steroid derivative containing a metallocene moiety, was stereoselectively prepared (see scheme). The key steps included the enantioselective functionalization of ferrocene, elongation of the side chain, intramolecular enyne metathesis, Diels–Alder reaction, heterogeneous hydrogenation of the sterically hindered double bond, and finally inversion of the configuration at C13. Ferrocenestrone, the first steroid derivative containing a metallocene moiety, was stereoselectively prepared (see scheme). The key steps included the enantioselective functionalization of ferrocene, elongation of the side chain, intramolecular enyne metathesis, Diels–Alder reaction, heterogeneous hydrogenation of the sterically hindered double bond, and finally inversion of the configuration at C13.
dcterms:title
Synthesis of ferrocenestrone: the first metallocene based steroid analogue Synthesis of ferrocenestrone: the first metallocene based steroid analogue
skos:prefLabel
Synthesis of ferrocenestrone: the first metallocene based steroid analogue Synthesis of ferrocenestrone: the first metallocene based steroid analogue
skos:notation
RIV/68378050:_____/12:00387886!RIV13-GA0-68378050
n3:predkladatel
n17:ico%3A68378050
n4:aktivita
n5:P n5:Z n5:I
n4:aktivity
I, P(1M0508), P(GA204/09/1905), P(LC06077), Z(MSM0021620857)
n4:cisloPeriodika
18
n4:dodaniDat
n7:2013
n4:domaciTvurceVysledku
n6:3634566 n6:9407219
n4:druhVysledku
n19:J
n4:duvernostUdaju
n9:S
n4:entitaPredkladatele
n18:predkladatel
n4:idSjednocenehoVysledku
172961
n4:idVysledku
RIV/68378050:_____/12:00387886
n4:jazykVysledku
n16:eng
n4:klicovaSlova
asymmetric synthesis; ferrocenestrones; metallocenes; steroids; synthesis design
n4:klicoveSlovo
n11:ferrocenestrones n11:steroids n11:synthesis%20design n11:metallocenes n11:asymmetric%20synthesis
n4:kodStatuVydavatele
DE - Spolková republika Německo
n4:kontrolniKodProRIV
[6B80A65CBD9A]
n4:nazevZdroje
Chemistry - A European Journal
n4:obor
n14:EB
n4:pocetDomacichTvurcuVysledku
2
n4:pocetTvurcuVysledku
5
n4:projekt
n13:LC06077 n13:1M0508 n13:GA204%2F09%2F1905
n4:rokUplatneniVysledku
n7:2012
n4:svazekPeriodika
18
n4:tvurceVysledku
Císařová, I. Kotora, Martin Bartůněk, Petr Hessler, F. Sedlák, David
n4:wos
000302991600007
n4:zamer
n10:MSM0021620857
s:issn
0947-6539
s:numberOfPages
4
n20:doi
10.1002/chem.201200687