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Statements

Subject Item
n2:RIV%2F68081707%3A_____%2F14%3A00428338%21RIV15-AV0-68081707
rdf:type
skos:Concept n12:Vysledek
dcterms:description
In this study, the screening steps of chiral separation strategies with polysaccharide-based chiral stationary phases were applied on boron cluster compounds in normal-phase liquid chromatography (NPLC) and polar organic solvents chromatography (POSC). Since the screening steps were initially developed to analyze organic compounds, their applicability for boron clusters was investigated. Overall, the screening steps in NPLC were applicable for the separation of zwitterions, while for anions mostly no elution was observed. A hypothesis for the latter behavior is precipitation of anions in the nonpolar mobile phases. Ten out of 11 compounds could be partially or baseline separated on the NPLC screening systems. In POSC, all zwitterions were separated on at least one of the screening systems, with an overall lower retention as in NPLC. Anions were detected but not separated in the majority of the experiments. Also their retention on the chiral stationary phases was very limited. In this study, the screening steps of chiral separation strategies with polysaccharide-based chiral stationary phases were applied on boron cluster compounds in normal-phase liquid chromatography (NPLC) and polar organic solvents chromatography (POSC). Since the screening steps were initially developed to analyze organic compounds, their applicability for boron clusters was investigated. Overall, the screening steps in NPLC were applicable for the separation of zwitterions, while for anions mostly no elution was observed. A hypothesis for the latter behavior is precipitation of anions in the nonpolar mobile phases. Ten out of 11 compounds could be partially or baseline separated on the NPLC screening systems. In POSC, all zwitterions were separated on at least one of the screening systems, with an overall lower retention as in NPLC. Anions were detected but not separated in the majority of the experiments. Also their retention on the chiral stationary phases was very limited.
dcterms:title
Chiral separability of boron cluster species studied by screening approaches utilizing polysaccharide-based chiral stationary phases Chiral separability of boron cluster species studied by screening approaches utilizing polysaccharide-based chiral stationary phases
skos:prefLabel
Chiral separability of boron cluster species studied by screening approaches utilizing polysaccharide-based chiral stationary phases Chiral separability of boron cluster species studied by screening approaches utilizing polysaccharide-based chiral stationary phases
skos:notation
RIV/68081707:_____/14:00428338!RIV15-AV0-68081707
n4:aktivita
n7:I
n4:aktivity
I
n4:cisloPeriodika
5
n4:dodaniDat
n10:2015
n4:domaciTvurceVysledku
n16:1458027
n4:druhVysledku
n6:J
n4:duvernostUdaju
n17:S
n4:entitaPredkladatele
n15:predkladatel
n4:idSjednocenehoVysledku
7152
n4:idVysledku
RIV/68081707:_____/14:00428338
n4:jazykVysledku
n14:eng
n4:klicovaSlova
SUPERCRITICAL-FLUID CHROMATOGRAPHY; ORGANIC-SOLVENT CHROMATOGRAPHY; LIQUID-CHROMATOGRAPHY
n4:klicoveSlovo
n5:SUPERCRITICAL-FLUID%20CHROMATOGRAPHY n5:ORGANIC-SOLVENT%20CHROMATOGRAPHY n5:LIQUID-CHROMATOGRAPHY
n4:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n4:kontrolniKodProRIV
[595AB373A4C9]
n4:nazevZdroje
Biomedical Chromatography
n4:obor
n13:BO
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
3
n4:rokUplatneniVysledku
n10:2014
n4:svazekPeriodika
28
n4:tvurceVysledku
Mangelings, D. Vander Heyden, Y. Vespalec, Radim
n4:wos
000334197400016
s:issn
0269-3879
s:numberOfPages
14
n8:doi
10.1002/bmc.3091