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Statements

Subject Item
n2:RIV%2F68081707%3A_____%2F13%3A00399496%21RIV14-AV0-68081707
rdf:type
n14:Vysledek skos:Concept
dcterms:description
The interaction between the thrombin binding aptamer (TBA), a G-quadruplex forming DNA sequence, and the electroactive hexaammineruthenium(III) cation has been studied by electrochemical methods and circular dichroism spectroscopy. When TBA is immobilised on a gold surface in a typical aptasensor configuration, the [Ru(NH3)(6)](3+) cation can be bound to the electrode surface through its interaction with the TBA sequence. This interaction is strong enough to enable-the-ruthenium complex-to remain at the surface when the electrode is immersed in an electrolyte free of [Ru(NH3)(6)](3+), meaning that the complex does not diffuse back into the solution. The interaction between the thrombin binding aptamer (TBA), a G-quadruplex forming DNA sequence, and the electroactive hexaammineruthenium(III) cation has been studied by electrochemical methods and circular dichroism spectroscopy. When TBA is immobilised on a gold surface in a typical aptasensor configuration, the [Ru(NH3)(6)](3+) cation can be bound to the electrode surface through its interaction with the TBA sequence. This interaction is strong enough to enable-the-ruthenium complex-to remain at the surface when the electrode is immersed in an electrolyte free of [Ru(NH3)(6)](3+), meaning that the complex does not diffuse back into the solution.
dcterms:title
On the interaction between [Ru(NH3)(6)](3+) and the G-quadruplex forming thrombin binding aptamer sequence On the interaction between [Ru(NH3)(6)](3+) and the G-quadruplex forming thrombin binding aptamer sequence
skos:prefLabel
On the interaction between [Ru(NH3)(6)](3+) and the G-quadruplex forming thrombin binding aptamer sequence On the interaction between [Ru(NH3)(6)](3+) and the G-quadruplex forming thrombin binding aptamer sequence
skos:notation
RIV/68081707:_____/13:00399496!RIV14-AV0-68081707
n14:predkladatel
n17:ico%3A68081707
n3:aktivita
n12:I
n3:aktivity
I
n3:cisloPeriodika
SEP 2013
n3:dodaniDat
n4:2014
n3:domaciTvurceVysledku
n10:7624352
n3:druhVysledku
n8:J
n3:duvernostUdaju
n5:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
93892
n3:idVysledku
RIV/68081707:_____/13:00399496
n3:jazykVysledku
n16:eng
n3:klicovaSlova
SELF-ASSEMBLED MONOLAYERS; DNA-MODIFIED SURFACES; CIRCULAR-DICHROISM
n3:klicoveSlovo
n15:SELF-ASSEMBLED%20MONOLAYERS n15:DNA-MODIFIED%20SURFACES n15:CIRCULAR-DICHROISM
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[2BDF97A6D10E]
n3:nazevZdroje
Journal of Inorganic Biochemistry
n3:obor
n18:BO
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:rokUplatneniVysledku
n4:2013
n3:svazekPeriodika
126
n3:tvurceVysledku
Kejnovská, Iva Doneux, T. Buess-Herman, C. De Rache, A.
n3:wos
000322942400012
s:issn
0162-0134
s:numberOfPages
7
n11:doi
10.1016/j.jinorgbio.2013.05.014