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Statements

Subject Item
n2:RIV%2F68081707%3A_____%2F13%3A00394828%21RIV14-GA0-68081707
rdf:type
skos:Concept n10:Vysledek
dcterms:description
Chronopotentiometric stripping (CPS) peak H in proteins is due to the catalytic hydrogen evolution reaction (CHER) involving amino acid residues. This peak is sensitive to changes in protein structures, representing a new tool in protein research. Here we show on the ground of studies of CPS behavior of four angiotensin peptides that at neutral pH arginine plays a critical role in CHER at Hg electrode, while participation of histidine residues in this reaction is very weak. At carbon electrode tyrosine residues produce an oxidation peak close to 0.7 V but the presence of histidine in angiotensins is not manifested by any oxidation peak. (C) 2013 Elsevier B.V. All rights reserved. Chronopotentiometric stripping (CPS) peak H in proteins is due to the catalytic hydrogen evolution reaction (CHER) involving amino acid residues. This peak is sensitive to changes in protein structures, representing a new tool in protein research. Here we show on the ground of studies of CPS behavior of four angiotensin peptides that at neutral pH arginine plays a critical role in CHER at Hg electrode, while participation of histidine residues in this reaction is very weak. At carbon electrode tyrosine residues produce an oxidation peak close to 0.7 V but the presence of histidine in angiotensins is not manifested by any oxidation peak. (C) 2013 Elsevier B.V. All rights reserved.
dcterms:title
Electrochemical reduction and oxidation signals of angiotensin peptides. Role of individual amino acid residues Electrochemical reduction and oxidation signals of angiotensin peptides. Role of individual amino acid residues
skos:prefLabel
Electrochemical reduction and oxidation signals of angiotensin peptides. Role of individual amino acid residues Electrochemical reduction and oxidation signals of angiotensin peptides. Role of individual amino acid residues
skos:notation
RIV/68081707:_____/13:00394828!RIV14-GA0-68081707
n10:predkladatel
n11:ico%3A68081707
n3:aktivita
n9:P n9:I
n3:aktivity
I, P(GAP301/11/2055)
n3:cisloPeriodika
JUN 2013
n3:dodaniDat
n6:2014
n3:domaciTvurceVysledku
n13:6281044 n13:9991646 n13:1424726
n3:druhVysledku
n14:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n7:predkladatel
n3:idSjednocenehoVysledku
72362
n3:idVysledku
RIV/68081707:_____/13:00394828
n3:jazykVysledku
n18:eng
n3:klicovaSlova
CARBON ELECTRODES; HYDROGEN EVOLUTION; BIOACTIVE PEPTIDES
n3:klicoveSlovo
n15:CARBON%20ELECTRODES n15:HYDROGEN%20EVOLUTION n15:BIOACTIVE%20PEPTIDES
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[740DBE5041D9]
n3:nazevZdroje
Electrochemistry Communications
n3:obor
n17:BO
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:projekt
n8:GAP301%2F11%2F2055
n3:rokUplatneniVysledku
n6:2013
n3:svazekPeriodika
31
n3:tvurceVysledku
Ostatná, Veronika Paleček, Emil Dorčák, Vlastimil
n3:wos
000319236800022
s:issn
1388-2481
s:numberOfPages
4
n19:doi
10.1016/j.elecom.2013.03.016