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Statements

Subject Item
n2:RIV%2F68081707%3A_____%2F12%3A00440812%21RIV15-GA0-68081707
rdf:type
skos:Concept n12:Vysledek
dcterms:description
Adsorption and two-dimensional (2D) condensation of 5-fluotocytosine on hanging mercury drop electrode is studied in this work. 5-fluorocytosine is an important derivative of cytosine which is widely used in pharmacology. The influence of concentration, temperature pH and electrolyte composition on the 2D condensation of 5-fluorocytosine was investigated by differential capacitance measurements. Three capacitance pits associated with the formation of 2D compact layers are evidenced. One film, formed at potential slightly negative from the potential of zero charge of the electrode, involves both neutral and protonated 5-fluorocytosine molecules. At highly negatively charged electrodes, dipole-induced orientation of 5-fluorocytosine leads to the formation of two additional 2D layers. One of them is found to result from the interaction of 5-fluorocytosine with acetic acid, present in the buffer electrolyte. Adsorption and two-dimensional (2D) condensation of 5-fluotocytosine on hanging mercury drop electrode is studied in this work. 5-fluorocytosine is an important derivative of cytosine which is widely used in pharmacology. The influence of concentration, temperature pH and electrolyte composition on the 2D condensation of 5-fluorocytosine was investigated by differential capacitance measurements. Three capacitance pits associated with the formation of 2D compact layers are evidenced. One film, formed at potential slightly negative from the potential of zero charge of the electrode, involves both neutral and protonated 5-fluorocytosine molecules. At highly negatively charged electrodes, dipole-induced orientation of 5-fluorocytosine leads to the formation of two additional 2D layers. One of them is found to result from the interaction of 5-fluorocytosine with acetic acid, present in the buffer electrolyte.
dcterms:title
Two-dimensional condensation of 5-fluorocytosine at the mercury electrode Two-dimensional condensation of 5-fluorocytosine at the mercury electrode
skos:prefLabel
Two-dimensional condensation of 5-fluorocytosine at the mercury electrode Two-dimensional condensation of 5-fluorocytosine at the mercury electrode
skos:notation
RIV/68081707:_____/12:00440812!RIV15-GA0-68081707
n3:aktivita
n8:I n8:P
n3:aktivity
I, P(GAP205/10/2378), P(LC06035)
n3:cisloPeriodika
SI
n3:dodaniDat
n10:2015
n3:domaciTvurceVysledku
n11:6245420 n11:7746547
n3:druhVysledku
n7:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
175489
n3:idVysledku
RIV/68081707:_____/12:00440812
n3:jazykVysledku
n5:eng
n3:klicovaSlova
2D condensation; Hanging mercury drop electrode; 5-Fluorocytosine
n3:klicoveSlovo
n14:2D%20condensation n14:Hanging%20mercury%20drop%20electrode n14:5-Fluorocytosine
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[F0DF5015CA7A]
n3:nazevZdroje
Electrochimica acta
n3:obor
n9:BO
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
3
n3:projekt
n13:GAP205%2F10%2F2378 n13:LC06035
n3:rokUplatneniVysledku
n10:2012
n3:svazekPeriodika
73
n3:tvurceVysledku
Doneux, T. Fojt, Lukáš Vetterl, Vladimír
n3:wos
000305261100022
s:issn
0013-4686
s:numberOfPages
4
n18:doi
10.1016/j.electacta.2011.12.061