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Statements

Subject Item
n2:RIV%2F67985858%3A_____%2F12%3A00398556%21RIV14-TA0-67985858
rdf:type
skos:Concept n14:Vysledek
dcterms:description
Paper deals with design of pilot reactor for low temperature N2O decomposition in off-gases from HNO3 production. Pseudo-homogeneous one-dimensional model of an ideal plug flow reactor was used for modeling of N2O decomposition in a laboratory fixed bed reactor filled with grains or pellets of a Co–Mn–Al mixed oxide catalyst. Increase in inlet pressure up to 0.6 MPa did not influence the effective diffusion coefficient, but improved the achieved N2O conversion. Based on the laboratory data of N2O decomposition over Co–Mn–Al mixed oxide pellets, catalyst bed of 3400 kg was estimated for target 90% N2O conversion (30 000 m3 h1 of exhaust gases from HNO3 plant containing 0.1 molar% N2O, 0.01 molar% NO, 0.01 molar% NO2, 3 molar% H2O, 5 molar% O2) at 420 °C and 600 kPa inlet pressure. Paper deals with design of pilot reactor for low temperature N2O decomposition in off-gases from HNO3 production. Pseudo-homogeneous one-dimensional model of an ideal plug flow reactor was used for modeling of N2O decomposition in a laboratory fixed bed reactor filled with grains or pellets of a Co–Mn–Al mixed oxide catalyst. Increase in inlet pressure up to 0.6 MPa did not influence the effective diffusion coefficient, but improved the achieved N2O conversion. Based on the laboratory data of N2O decomposition over Co–Mn–Al mixed oxide pellets, catalyst bed of 3400 kg was estimated for target 90% N2O conversion (30 000 m3 h1 of exhaust gases from HNO3 plant containing 0.1 molar% N2O, 0.01 molar% NO, 0.01 molar% NO2, 3 molar% H2O, 5 molar% O2) at 420 °C and 600 kPa inlet pressure.
dcterms:title
N2O Catalytic Decomposition – from Laboratory Experiment to Industry Reactor N2O Catalytic Decomposition – from Laboratory Experiment to Industry Reactor
skos:prefLabel
N2O Catalytic Decomposition – from Laboratory Experiment to Industry Reactor N2O Catalytic Decomposition – from Laboratory Experiment to Industry Reactor
skos:notation
RIV/67985858:_____/12:00398556!RIV14-TA0-67985858
n14:predkladatel
n18:ico%3A67985858
n3:aktivita
n15:P n15:I
n3:aktivity
I, P(TA01020336)
n3:cisloPeriodika
1
n3:dodaniDat
n6:2014
n3:domaciTvurceVysledku
n17:8799938
n3:druhVysledku
n13:J
n3:duvernostUdaju
n11:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
155186
n3:idVysledku
RIV/67985858:_____/12:00398556
n3:jazykVysledku
n16:eng
n3:klicovaSlova
N2O; catalytic decomposition; fixed bed reactor
n3:klicoveSlovo
n5:N2O n5:fixed%20bed%20reactor n5:catalytic%20decomposition
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[A05A686CB43D]
n3:nazevZdroje
Catalysis Today
n3:obor
n4:CI
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:projekt
n9:TA01020336
n3:rokUplatneniVysledku
n6:2012
n3:svazekPeriodika
191
n3:tvurceVysledku
Chromčáková, Ž. Jirátová, Květa Obalová, L. Karásková, K.
n3:wos
000308675000020
s:issn
0920-5861
s:numberOfPages
5
n10:doi
10.1016/j.cattod.2012.03.045