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Statements

Subject Item
n2:RIV%2F67985858%3A_____%2F12%3A00383459%21RIV13-AV0-67985858
rdf:type
skos:Concept n13:Vysledek
dcterms:description
Carbosilane metallodendrimers containing substituted titanocene dichloride end groups were prepared using hydrosilylation as the capping reaction. Two complementary pathways were followed: hydrosilylation of ω-alkenyl-substituted titanocene dichloride complexes with SiH bond terminated dendrimers and hydrosilylation of vinyl terminated dendritic materials with 3-(dimethylsilyl)propyl-substituted titanocene dichloride. The former procedure provided dendrimers of the first generation with four end units and of the second generation with eight end units. The latter method gave dendrititic wedges and dendrimers up to the second generation with 16 peripheral titanocene dichloride units and molecular weight 7070 Da. Dendritic materials were purified by GPC and characterized by MALDI-TOF mass spectrometry and ESI-TOF mass spectrometry (metallodendrimers) and also by multinuclear NMR. Carbosilane metallodendrimers containing substituted titanocene dichloride end groups were prepared using hydrosilylation as the capping reaction. Two complementary pathways were followed: hydrosilylation of ω-alkenyl-substituted titanocene dichloride complexes with SiH bond terminated dendrimers and hydrosilylation of vinyl terminated dendritic materials with 3-(dimethylsilyl)propyl-substituted titanocene dichloride. The former procedure provided dendrimers of the first generation with four end units and of the second generation with eight end units. The latter method gave dendrititic wedges and dendrimers up to the second generation with 16 peripheral titanocene dichloride units and molecular weight 7070 Da. Dendritic materials were purified by GPC and characterized by MALDI-TOF mass spectrometry and ESI-TOF mass spectrometry (metallodendrimers) and also by multinuclear NMR.
dcterms:title
Carbosilane Metallodendrimers with Titanocene Dichloride end Groups Carbosilane Metallodendrimers with Titanocene Dichloride end Groups
skos:prefLabel
Carbosilane Metallodendrimers with Titanocene Dichloride end Groups Carbosilane Metallodendrimers with Titanocene Dichloride end Groups
skos:notation
RIV/67985858:_____/12:00383459!RIV13-AV0-67985858
n13:predkladatel
n14:ico%3A67985858
n4:aktivita
n17:P n17:I
n4:aktivity
I, P(LC06070)
n4:cisloPeriodika
19
n4:dodaniDat
n16:2013
n4:domaciTvurceVysledku
n8:6618669 n8:8828598 n8:1437380
n4:druhVysledku
n18:J
n4:duvernostUdaju
n11:S
n4:entitaPredkladatele
n12:predkladatel
n4:idSjednocenehoVysledku
125985
n4:idVysledku
RIV/67985858:_____/12:00383459
n4:jazykVysledku
n19:eng
n4:klicovaSlova
dendrimers; titanocene; hydrosilylation
n4:klicoveSlovo
n6:titanocene n6:hydrosilylation n6:dendrimers
n4:kodStatuVydavatele
US - Spojené státy americké
n4:kontrolniKodProRIV
[E2CA771C8308]
n4:nazevZdroje
Organometallics
n4:obor
n15:CC
n4:pocetDomacichTvurcuVysledku
3
n4:pocetTvurcuVysledku
7
n4:projekt
n7:LC06070
n4:rokUplatneniVysledku
n16:2012
n4:svazekPeriodika
31
n4:tvurceVysledku
Jaroschik, F. Harakat, D. Walterová, Zuzana Sýkora, Jan Horský, Jiří Strašák, Tomáš Čermák, Jan
n4:wos
000309488500009
s:issn
0276-7333
s:numberOfPages
8
n5:doi
10.1021/om300559y