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Statements

Subject Item
n2:RIV%2F67985858%3A_____%2F12%3A00375563%21RIV13-AV0-67985858
rdf:type
skos:Concept n8:Vysledek
dcterms:description
Dendritic polyols of the second and third generation 2G-OH8 (1), 2G-OH16 (2), and 3G-OH16 (3) were prepared by hydroboration/oxidation of allyl-terminated carbosilane dendrimers and used as supports for the immobilization of cyclopentadienyltrichlorotitanium(IV) complexes via alcoholysis. The reaction of 1 - 3 with CpTiCl3 gave metallodendrimers 2G-(OTiCpCl2)8 (4a), 2G-(OTiCpCl2)16 (5a), and 3G-(OTiCpCl2)16 (6a), respectively, whereas the reaction of 1 and 3 with CpSiFTiCl3 (CpSiF = C5H4SiMe2CH2CH2C8F17) yielded peripherally fluorinated metallodendrimers 2G-(OTiCpSiFCl2)8 (4b) and 3G-(OTiCpSiFCl2)16 (6b). The suggested structures were supported by comparison with model 1-propoxycomplexes 10a,b. To identify side products of the alcoholysis reaction, hydrolytic behavior of the starting trichloro complexes was studied both in solid state and in solution. Dendritic polyols of the second and third generation 2G-OH8 (1), 2G-OH16 (2), and 3G-OH16 (3) were prepared by hydroboration/oxidation of allyl-terminated carbosilane dendrimers and used as supports for the immobilization of cyclopentadienyltrichlorotitanium(IV) complexes via alcoholysis. The reaction of 1 - 3 with CpTiCl3 gave metallodendrimers 2G-(OTiCpCl2)8 (4a), 2G-(OTiCpCl2)16 (5a), and 3G-(OTiCpCl2)16 (6a), respectively, whereas the reaction of 1 and 3 with CpSiFTiCl3 (CpSiF = C5H4SiMe2CH2CH2C8F17) yielded peripherally fluorinated metallodendrimers 2G-(OTiCpSiFCl2)8 (4b) and 3G-(OTiCpSiFCl2)16 (6b). The suggested structures were supported by comparison with model 1-propoxycomplexes 10a,b. To identify side products of the alcoholysis reaction, hydrolytic behavior of the starting trichloro complexes was studied both in solid state and in solution.
dcterms:title
Carbosilane Metallodendrimers with Cyclopentadienyldichlorotitanium(IV) End Groups Carbosilane Metallodendrimers with Cyclopentadienyldichlorotitanium(IV) End Groups
skos:prefLabel
Carbosilane Metallodendrimers with Cyclopentadienyldichlorotitanium(IV) End Groups Carbosilane Metallodendrimers with Cyclopentadienyldichlorotitanium(IV) End Groups
skos:notation
RIV/67985858:_____/12:00375563!RIV13-AV0-67985858
n8:predkladatel
n16:ico%3A67985858
n3:aktivita
n14:P n14:Z
n3:aktivity
P(LC06070), Z(AV0Z40720504)
n3:cisloPeriodika
2
n3:dodaniDat
n4:2013
n3:domaciTvurceVysledku
n15:7290322 n15:1437380
n3:druhVysledku
n13:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
125984
n3:idVysledku
RIV/67985858:_____/12:00375563
n3:jazykVysledku
n11:eng
n3:klicovaSlova
carbosilane dendrimers; cyclopentadienyl ligands; fluorine-containing ligands
n3:klicoveSlovo
n7:fluorine-containing%20ligands n7:carbosilane%20dendrimers n7:cyclopentadienyl%20ligands
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[B33E322EE7F1]
n3:nazevZdroje
Journal of Inorganic and Organometallic Polymers and Materials
n3:obor
n9:CC
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:projekt
n5:LC06070
n3:rokUplatneniVysledku
n4:2012
n3:svazekPeriodika
22
n3:tvurceVysledku
Čermák, Jan Krupková, Alena
n3:wos
000301522300022
n3:zamer
n20:AV0Z40720504
s:issn
1574-1443
s:numberOfPages
8
n17:doi
10.1007/s10904-011-9632-1